Deciphering structure and aggregation in asphaltenes: hypothesis-driven design and development of synthetic model compounds

DE Scott, M Schulze, JM Stryker… - Chemical Society …, 2021 - pubs.rsc.org
Asphaltenes comprise the heaviest and least understood fraction of crude petroleum. The
asphaltenes are a diverse and complex mixture of organic and organometallic molecules in …

Investigating the bio-rejuvenator effects on aged asphalt through exploring molecular evolution and chemical transformation of asphalt components during oxidative …

D Hu, X Gu, Q Dong, L Lyu, B Cui, J Pei - Journal of Cleaner Production, 2021 - Elsevier
Using a rejuvenator to increase the dose of reclaimed asphalt pavement (RAP) materials in
asphalt mixtures is a sustainable practice in the pavement industry. However, the …

Lessons learned from a decade-long assessment of asphaltenes by ultrahigh-resolution mass spectrometry and implications for complex mixture analysis

ML Chacon-Patino, MR Gray, C Rüger… - Energy & …, 2021 - ACS Publications
Recent advances in instrumentation for high-field Fourier transform ion cyclotron resonance
mass spectrometry (FT-ICR MS) have enabled access to∼ 70 000 unique molecular …

Mesoscale dissipative particle dynamics to investigate oil asphaltenes and sodium naphthenates at the oil− water interface

Y Ruiz-Morales, F Alvarez-Ramírez - Energy & Fuels, 2021 - ACS Publications
The effect of the structure of oil asphaltenes and sodium naphthenates at the oil–water
interface on the reduction of the oil–water interfacial tension and the formation of stable …

Applications of noncontact atomic force microscopy in petroleum characterization: Opportunities and challenges

Y Zhang - Energy & Fuels, 2021 - ACS Publications
Despite a tremendous amount of research, molecular characterization of petroleum remains
a significant scientific challenge because petroleum is an exceptionally complex molecular …

Structure–dynamic function relations of asphaltenes

L Zhang, P Chen, S Pan, F Liu, V Pauchard… - Energy & …, 2021 - ACS Publications
Asphaltene molecular and nanocolloidal structures have largely been resolved enabling
development of structure–function relations of asphaltenes. Atomic force microscopy (AFM) …

The role of methyl groups in the early stage of thermal polymerization of polycyclic aromatic hydrocarbons revealed by molecular imaging

P Chen, S Fatayer, B Schuler, JN Metz, L Gross… - Energy & …, 2021 - ACS Publications
The initial thermal reactions of aromatic hydrocarbons are relevant to many industrial
applications. However, tracking the growing number of heavy polycyclic aromatic …

Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation

X Li, K Niu, J Zhang, X Yu, H Zhang… - National Science …, 2021 - academic.oup.com
Abstract Selective C (sp3)− H activation is of fundamental importance in processing alkane
feedstocks to produce high-value-added chemical products. By virtue of an on-surface …

Ex Situ and In Situ Thermal Transformations of M-50 Pitch Revealed by Non-contact Atomic Force Microscopy

P Chen, JN Metz, AS Gross, SE Smith, SP Rucker… - Energy & …, 2021 - ACS Publications
Petroleum pitch M-50 (or A-240) has been well-known in making valuable carbon materials
through thermal treatments. How these molecules react to produce carbon materials and the …

On-surface synthesis and molecular engineering of carbon-based nanoarchitectures

L Li, S Mahapatra, D Liu, Z Lu, N Jiang - ACS nano, 2021 - ACS Publications
On-surface synthesis via covalent coupling of adsorbed precursor molecules on metal
surfaces has emerged as a promising strategy for the design and fabrication of novel …