Designing supramolecular polymers with nucleation and growth processes

EP Bruckner, SI Stupp - Polymer International, 2022 - Wiley Online Library
The self‐assembly of small molecules into supramolecular polymers can be analogous to
the formation of classical solid‐state crystals depending on the mechanism of …

Thermoreversible Polymorph Transitions in Supramolecular Polymers of Hydrogen‐Bonded Squaramides

S Bujosa, A Doncel‐Giménez, N Bäumer… - Angewandte Chemie …, 2022 - Wiley Online Library
Hydrogen‐bonded squaramide (SQ) supramolecular polymers exhibit uncommon
thermoreversible polymorph transitions between particle‐and fiber‐like nanostructures. SQs …

Desymmetrization via activated esters enables rapid synthesis of multifunctional benzene-1, 3, 5-tricarboxamides and creation of supramolecular hydrogelators

S Hafeez, HW Ooi, D Suylen, H Duimel… - Journal of the …, 2022 - ACS Publications
Supramolecular materials based on the self-assembly of benzene-1, 3, 5-tricarboxamide
(BTA) offer an approach to mimic fibrous self-assembled proteins found in numerous natural …

[HTML][HTML] Photo-modulation of supramolecular polymorphism in the self-assembly of a scissor-shaped azobenzene dyad into nanotoroids and fibers

N Suda, T Saito, H Arima, S Yagai - Chemical Science, 2022 - pubs.rsc.org
Recent advances in the research field of supramolecularly engineered dye aggregates have
enabled the design of simple one-dimensional stacks such as fibers and of closed structures …

Reversible Supramolecular Polymorphism in Solution and Solid Matrix by Manipulating Sidegroup Conformation

S Datta, D Chaudhuri - Angewandte Chemie International …, 2022 - Wiley Online Library
Reversible switching between supramolecular polymorphs offers a great way to introduce
stimuli‐responsiveness. Supramolecular polymorphism is usually achieved through …

[HTML][HTML] Selection of diverse polymorphic structures from a small dynamic molecular network controlled by the environment

B Bartolec, A Kiani, MA Beatty, M Altay… - Chemical …, 2022 - pubs.rsc.org
The complex interplay between systems and their environment plays an important role in
processes ranging from self-assembly to evolution. Polymorphism, where, from the same …

Complex supramolecular fiber formed by coordination-induced self-assembly of benzene-1, 3, 5-tricarboxamide (BTA)

B Wu, L Liu, L Zhou, JR Magana… - Journal of Colloid and …, 2022 - Elsevier
Hypothesis In the quest for large but well-controlled supramolecular structures, the discotic
benzene-1, 3, 5-tricarboxamide (BTA) has received quite some attention, because it can …

Supramolecular chiral assembly of symmetric molecules with an extended conjugated core

J Wu, J Zhang, Y Liu, J Wang, C Zhang… - … Applied Materials & …, 2022 - ACS Publications
C3-symmetric molecules carrying a conjugated diacetylene (DA) core are found to self-
assemble into well-defined supramolecular fibers with enhanced supramolecular chirality in …

[HTML][HTML] Self-assembly of an MRI responsive agent under physiological conditions provides an extended time window for in vivo imaging

ND Tirukoti, L Avram, R Mashiach… - Chemical …, 2022 - pubs.rsc.org
An MRI-responsive agent that spontaneously self-assembles to a large supramolecular
structure under physiological conditions was designed. The obtained assembly provides an …

Micelle and nanotape formation of Benzene Tricarboxamide analogues with selective cancer cell cytotoxicity

N Aljuaid, J Seitsonen, J Ruokolainen, F Greco… - ACS …, 2022 - ACS Publications
Analogues of benzene-1, 3, 5-tricarboxamide bearing combinations of different alkyl chains
(dodecyl to octadecyl) and ester-linked PEG (polyethylene glycol) chains are shown to self …