Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …
[HTML][HTML] Unusual structures and unknown roles of FeS clusters in metalloenzymes seen from a resonance Raman spectroscopic perspective
G Caserta, L Zuccarello, C Barbosa, CM Silveira… - Coordination Chemistry …, 2022 - Elsevier
The universe of known biological FeS clusters is constantly enlarging. Besides the
conventional, well described [2Fe–2S],[3Fe–4S] and cubane [4Fe–4S] clusters, novel …
conventional, well described [2Fe–2S],[3Fe–4S] and cubane [4Fe–4S] clusters, novel …
Aerobic hydrogen-oxidizing bacteria in soil: from cells to ecosystems
X Fan, X Zhang, G Zhao, X Zhang, L Dong… - … in Environmental Science …, 2022 - Springer
Aerobic hydrogen-oxidizing bacteria (HOB) is a group of active, abundant, and diverse
microorganisms with representatives in nearly all phyla, distributed in soil exposed to …
microorganisms with representatives in nearly all phyla, distributed in soil exposed to …
[HTML][HTML] Harnessing selenocysteine to enhance microbial cell factories for hydrogen production
Hydrogen is a clean, renewable energy source, that when combined with oxygen, produces
heat and electricity with only water vapor as a biproduct. Furthermore, it has the highest …
heat and electricity with only water vapor as a biproduct. Furthermore, it has the highest …
Insights from hydrogenase model studies on C–C bond forming reactions
S Ogo, T Yatabe, H Nakai - Coordination Chemistry Reviews, 2022 - Elsevier
In this review, we discuss whether the ligand design used in catalysts mimicking O 2-tolerant
[NiFe] hydrogenase ([NiFe] H 2 ase) can be applied to ligand design in catalysts for C–C …
[NiFe] hydrogenase ([NiFe] H 2 ase) can be applied to ligand design in catalysts for C–C …
Heteroleptic nickel complexes bearing O‐methyldithiophosphate and aminodiphosphine monosulfide ligands as robust molecular electrocatalysts for hydrogen …
L Chen, B Xie, T Li, C Lai, JX Cao, RW Ji… - Applied …, 2022 - Wiley Online Library
Five new heteroleptic nickel complexes containing O‐methyldithiophosphate and
aminodiphosphine monosulfide ligands,[Ni ((PPh2)({S} PPh2) NR)(S2P {O} …
aminodiphosphine monosulfide ligands,[Ni ((PPh2)({S} PPh2) NR)(S2P {O} …
Energy extraction from air: structural basis of atmospheric hydrogen oxidation
Diverse aerobic bacteria use atmospheric H2 as an energy source for growth and survival.
This recently discovered yet globally significant process regulates the composition of the …
This recently discovered yet globally significant process regulates the composition of the …
[HTML][HTML] Electrocatalytic hydrogen generation using tripod containing pyrazolylborate-based copper (II), nickel (II), and iron (III) complexes loaded on a glassy carbon …
Three transition metal complexes (MC) namely,[TpMeMeCuCl (H2O)](CuC),[TpMeMeNiCl](
NiC), and [TpMeMeFeCl2 (H2O)](FeC){TpMeMe= tris (3, 5-dimethylpyrazolyl) borate} were …
NiC), and [TpMeMeFeCl2 (H2O)](FeC){TpMeMe= tris (3, 5-dimethylpyrazolyl) borate} were …
Molecular concepts of water splitting and hydrogen production: Nature's approach
Photosynthesis is the most important chemical process on our planet [1, 2]. The invention of
water splitting by early photosynthetic organisms led to an oxygen-rich atmosphere and the …
water splitting by early photosynthetic organisms led to an oxygen-rich atmosphere and the …
Electrochemical H2 Production using Polypyrazole based Zinc (II) Complex in Alkaline Medium
A zinc (II) complex of polypyazole containing ligand namely,[Tp* ZnCl](Zn1){Tp*= tris (3, 5-
dimethylpyrazolyl) borate}, along with its zinc (II) bound hydroxo complex [Tp* Zn–OH](Zn2) …
dimethylpyrazolyl) borate}, along with its zinc (II) bound hydroxo complex [Tp* Zn–OH](Zn2) …