Homogeneity of Supported Single‐Atom Active Sites Boosting the Selective Catalytic Transformations

Y Shi, Y Zhou, Y Lou, Z Chen, H Xiong… - Advanced …, 2022 - Wiley Online Library
Selective conversion of specific functional groups to desired products is highly important but
still challenging in industrial catalytic processes. The adsorption state of surface species is …

Geometric and electronic effects in hydrogenation reactions

S Mao, Z Wang, Q Luo, B Lu, Y Wang - ACS Catalysis, 2022 - ACS Publications
Selective hydrogenation has a long history of being an important reaction process for the
preparation of high-value chemicals. The geometric and electronic structures of the catalysts …

Strategies for area-selective deposition of metal nanoparticles on carbon nanotubes and their applications: a review

F Olivares, F Peón, R Henríquez, RS del Río - Journal of Materials Science, 2022 - Springer
Carbon nanotubes (CNTs) have a common use as a nanostructured substrate to support
and stabilize metal nanoparticles (MNPs), generating hybrid materials whose properties can …

Synthesis of Dual-Active-Sites Ni-Ni2In catalysts for selective hydrogenation of furfural to furfuryl alcohol

K Yang, Y Li, R Wang, Q Li, B Huang, X Guo, Z Zhu… - Fuel, 2022 - Elsevier
The rational design of efficient heterogeneous catalysts for selective hydrogenation of
unsaturated aldehyde to unsaturated alcohol is a long-term scientific challenge and pursuit …

Geometrically embedding dispersive Pt nanoparticles within silicalite-1 framework for highly selective ɑ, β-unsaturated aldehydes hydrogenation via oriented C= O …

C Liu, P Zhu, J Wang, H Liu, X Zhang - Chemical Engineering Journal, 2022 - Elsevier
The issue for thermodynamically favored C= C hydrogenation needs to be overcome in the
hydrogenation of ɑ, β-unsaturated aldehydes to unsaturated alcohols. Herein, we employ …

Precise control of selective hydrogenation of α, β-unsaturated aldehydes in water mediated by ammonia borane

Y Zhou, C Chen, Q Li, Y Liu, T Wei, Y Liu, Z Zeng… - Applied Catalysis B …, 2022 - Elsevier
Hydrogenation of unsaturated biomass in a control manner is highly desirable but
challenging, especially under mild conditions. We here report selective hydrogenation of α …

Unraveling the reaction mechanism of selective C9 monomeric phenols formation from lignin using Pd-Al2O3-activated biochar catalyst

L Gurrala, MM Kumar, A Yerrayya, P Kandasamy… - Bioresource …, 2022 - Elsevier
The conversion of biomass-derived lignin to valuable monomeric phenols at high selectivity
is of paramount importance for sustainable biorefineries. In this study, a novel Pd-Al 2 O 3 …

Oxygen vacancy regulated selective hydrogenation of α, β-unsaturated aldehydes over LDH surface group coordinated transition metal photocatalysts

J Zhang, M Gao, R Wang, X Li, P Zhu… - Catalysis Science & …, 2022 - pubs.rsc.org
Selective hydrogenation of α, β-unsaturated aldehydes under mild conditions is a great
challenge in the synthesis of the corresponding alcohols. Herein, we report that a series of …

Pt‐WOx/C Catalysts for α, β‐Unsaturated Aldehydes Hydrogenation: An NMR Study of the Effect of the Reactant Adsorption on Activity and Selectivity

M Stucchi, F Vasile, S Cattaneo… - European Journal of …, 2022 - Wiley Online Library
The selective hydrogenation of α, β‐unsaturated aldehydes is an ideal case for studying the
structure‐activity relationships in heterogeneous catalysis. In particular, cinnamaldehyde …

Rapid detoxification of Microcystin-LR by selective catalytic hydrogenation of the Adda moiety using TiO2-supported Pd catalysts

J Sun, K Liu, PJJ Alvarez, H Fu, S Zheng, D Yin, X Qu - Chemosphere, 2022 - Elsevier
The hepatotoxicity of Microcystin-LR (MC-LR) is mainly caused by its Adda moiety. In this
study, we used TiO 2-supported Pd catalysts to selectively hydrogenate the Cdouble bondC …