Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Emerging trends on designing high-performance dysprosium (III) single-molecule magnets

TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

Recent advances in heterometallic clusters with f-block metal–metal bonds: synthesis, reactivity and applications

W Fang, Q Zhu, C Zhu - Chemical Society Reviews, 2022 - pubs.rsc.org
Due to the heterometallic synergistic effects from different metals, heterometallic clusters are
of great importance in small-molecule activation and catalysis. For example, both biological …

Organometallic lanthanide bismuth cluster single-molecule magnets

P Zhang, F Benner, NF Chilton, S Demir - Chem, 2022 - cell.com
Single-molecule magnets (SMMs) are molecules that can retain magnetic polarization in the
absence of an external magnetic field and embody the ultimate size limit for spin-based …

Synthesis and Magnetic Properties of Antimony-Ligated Co (II) Complexes: Stibines versus Phosphines

WV Taylor, BK Cashman, ZL Xie, KK Ngo… - Inorganic …, 2022 - ACS Publications
Herein, we test the hypothesis that neutral, heavy-atom stibine donors can increase the
extent of spin-orbit coupling on light, 3d transition metal. To this end, we developed a novel …

Subcomponent self-assembly of circular helical Dy6 (L) 6 and bipyramid Dy12 (L) 8 architectures directed via second-order template effects

XL Li, L Zhao, J Wu, W Shi, N Struch, A Lützen… - Chemical …, 2022 - pubs.rsc.org
In situ metal-templated (hydrazone) condensation also called subcomponent self-assembly
of 4, 6-dihydrazino-pyrimidine, o-vanillin and dysprosium ions resulted in the formation of …

Binuclear Triphenylantimony (V) Catecholates through N-Donor Linkers: Structural Features and Redox Properties

AI Poddel'sky, IV Smolyaninov, AI Shataeva… - Molecules, 2022 - mdpi.com
A series of binuclear triphenylantimony (V) bis-catecholato complexes 1–11 of the type (Cat)
Ph3Sb-linker-SbPh3 (Cat) was prepared by a reaction of the corresponding mononuclear …

Single-molecule magnets bridged by a bismuth Zintl ion

ZY Ruan, ML Tong - Chem, 2022 - cell.com
In this issue of Chem, Demir and colleagues report on the synthesis, ab initio calculations,
and magnetic behaviors of two organometallic lanthanide bismuth clusters involving an …

Polyimido Sulfur Compounds as Promising Ligands in Molecular Magnets

J Jung - 2022 - ediss.uni-goettingen.de
The beginning of sulfur nitrogen chemistry dates back to 1835 when GREGORY discovered
tetrasulfur tetranitride (S4N4).[6] The thermally unstable and shock-sensitive compound was …