Functional lanthanide complexes with N, N′-bis (2-hydroxybenzyl)-N, N′-bis (pyridin-2-ylmethyl) ethylenediamine (H2bbpen) derivatives: Coordination chemistry …

YX Qu, PY Liao, YC Chen, ML Tong - Coordination Chemistry Reviews, 2023 - Elsevier
Lanthanide complexes are among the most active frontiers of functional coordination
chemistry, especially due to their fascinating magnetic and optical properties. Among them …

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

K Bernot - European Journal of Inorganic Chemistry, 2023 - Wiley Online Library
The number of scientific articles that need to be considered to cover a research topic is ever‐
increasing and quite difficult for a newcomer to assimilate. This is particularly true in dynamic …

Air-stable four-coordinate cobalt (II) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic …

SK Gupta, SV Rao, S Demeshko, S Dechert, E Bill… - Chemical …, 2023 - pubs.rsc.org
For single-ion magnets (SIMs), understanding the effects of the local coordination
environment and ligand field on magnetic anisotropy is key to controlling their magnetic …

Significant Control on Zero‐Field Quantum Tunneling of Magnetization in Dysprosium Based Single‐Molecule Magnets via Orientation of the Anilato Ligand

P Kumar Sahu, A Mondal… - Chemistry–A European …, 2023 - Wiley Online Library
Tuning the bridging fashion of anilato ligand in dinuclear DyIII complexes, reveals a sizable
effect on the slow relaxation of magnetization. Combined experimental and theoretical …

Interplay of Anisotropic Exchange Interactions and Single-Ion Anisotropy in Single-Chain Magnets Built from Ru/Os Cyanidometallates (III) and Mn (III) Complex

VS Mironov, EV Peresypkina, KE Vostrikova - Molecules, 2023 - mdpi.com
Two novel 1D heterobimetallic compounds {[MnIII (SB2+) MIII (CN) 6]· 4H2O} n (SB2+= N,
N′-ethylenebis (5-trimethylammoniomethylsalicylideneiminate) based on orbitally …

Synthesis, crystal polymorphism and spin crossover behavior of adamantylboron-capped cobalt (ii) hexachloroclathrochelate and its transformation into the Co III Co II …

AS Belov, VV Novikov, AV Vologzhanina… - Dalton …, 2023 - pubs.rsc.org
Fast crystallization of the monoclathrochelate cobalt (II) intracomplex [Co (Cl2Gm) 3 (BAd)
2](where Cl2Gm2− is a dichloroglyoxime dianion and BAd is an adamantylboron capping …

Zero-Field Single-Molecule Magnet Behavior in a Series of Dinuclear Dysprosium (III) Complexes Based on Benzothiazolyl-Based Ligands and β-Diketonates

MH Wang, MY Tsai, YC Su, ST Chiu… - Crystal Growth & …, 2023 - ACS Publications
We report the synthesis and crystal structures of four dinuclear dysprosium (III) complexes
with the general formula (Dy2L2 x Y2)(1–4) based on the association of various flexible …

Triple-Decker Iron and Cobalt Complexes Featuring a Bridging 1, 2-Diboratabenzene Ligand

M Tamizmani, JR Tidwell, EW Reinheimer… - Inorganic …, 2023 - ACS Publications
Neutral triple-decker iron and cobalt complexes with a bridging 1, 2-diboratabenzene ligand
were accessed by reactions of a dilithium 1, 2-diboratabenzene reagent with [Cp* FeCl] 2 …

Russian Doll-like 3d–4f Cluster Wheels with Slow Relaxation of Magnetization

L Liu, P Yang, Z Qiu, K Wang, D Liu, Y Liang, H Hu… - Molecules, 2023 - mdpi.com
The solvothermal reactions of LnCl3· 6H2O and MCl2· 6H2O (M= Co, Ni) with 2, 2′-
diphenol (H2L1) and 5, 7-dichloro-8-hydroxyquinoline (HL2) gave three 3d–4f …

Multifunctional Ln III complexes with SMM, luminescence and MCE properties constructed using selected phosphine oxide and diketonate

H Yan, ZW Che, WB Sun - New Journal of Chemistry, 2023 - pubs.rsc.org
A series of mononuclear and binuclear lanthanideIII complexes with formulae [Dy
(Cy3PO)(tmhd) 3](1),[Dy2 (dppeO2)(tmhd) 6](2) and [Ln2 (dppeO2)(acac) 6 (H2O) 2](3, Ln …