Photocontrolled RAFT polymerization: past, present, and future
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …
[HTML][HTML] Radical-promoted single-unit monomer insertion (SUMI)[aka. reversible-deactivation radical addition (RDRA)]
We survey progress in the development of the processes for radical-promoted single-unit
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
Bulk depolymerization of poly (methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly
lower temperatures than previously reported methods through the incorporation of …
lower temperatures than previously reported methods through the incorporation of …
Inverse Miniemulsion Enables the Continuous-Flow Synthesis of Controlled Ultra-High Molecular Weight Polymers
CLG Davidson IV, ME Lott, L Trachsel… - ACS Macro …, 2023 - ACS Publications
We report the controlled synthesis of ultra-high molecular weight (UHMW) polymers (M n≥
106 g/mol) via continuous flow in a tubular reactor. At high monomer conversion, UHMW …
106 g/mol) via continuous flow in a tubular reactor. At high monomer conversion, UHMW …
Xanthate-supported photo-iniferter (XPI)-RAFT polymerization: facile and rapid access to complex macromolecules
Xanthate-supported photo-iniferter (XPI)-reversible addition–fragmentation chain-transfer
(RAFT) polymerization is introduced as a fast and versatile photo-polymerization strategy …
(RAFT) polymerization is introduced as a fast and versatile photo-polymerization strategy …
Step-growth polymerization by the RAFT process
Reversible Addition-Fragmentation Chain Transfer (RAFT) step-growth polymerization is an
emerging method that synergistically combines the benefits of RAFT polymerization …
emerging method that synergistically combines the benefits of RAFT polymerization …
Unraveling the Properties of Ultrahigh Molecular Weight Polyacrylates
LE Diodati, AJ Wong, ME Lott, AG Carter… - ACS Applied Polymer …, 2023 - ACS Publications
Photoiniferter polymerization is a straightforward method to produce well-defined ultrahigh
molecular weight (UHMW,> 1 MDa) acrylate polymers, which potentially provides access to …
molecular weight (UHMW,> 1 MDa) acrylate polymers, which potentially provides access to …
Installing a Single Monomer within Acrylic Polymers Using Photoredox Catalysis
Incorporating exactly one monomer at a defined position during a chain polymerization is
exceptionally challenging due to the statistical nature of monomer addition. Herein …
exceptionally challenging due to the statistical nature of monomer addition. Herein …
Manipulating fluorine induced bulky dipoles and their strong interaction to achieve high efficiency electric energy storage performance in polymer dielectrics
Y Cheng, Q Ji, B Zhu, X Zhang, H Gong… - Chemical Engineering …, 2023 - Elsevier
The pursuit of polymer dielectrics with elevated energy density frequently results in
heightened energy loss, thereby hindering practical applications. To decouple the …
heightened energy loss, thereby hindering practical applications. To decouple the …
Ultrafast Xanthate‐Mediated Photoiniferter Polymerization‐Induced Self‐Assembly (PISA)
Polymerization‐induced self‐assembly (PISA) is a powerful technique for preparing block
copolymer nanostructures. Recently, efforts have been focused on applying photochemistry …
copolymer nanostructures. Recently, efforts have been focused on applying photochemistry …