Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

Magnetic materials based on heterometallic Cr II/III–Ln III complexes

P Shukla, S Das, P Bag, A Dey - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Accommodating disparate spin centres within a single ensemble is a valuable synthetic
strategy to obtain interesting molecular magnetic materials. 3d–4f heterometallic complexes …

Chiral Zn3Ln3 Hexanuclear Clusters of an Achiral Flexible Ligand

L Miao, MJ Liu, M Zeng, HZ Kou - Inorganic Chemistry, 2023 - ACS Publications
Multifunctional single-molecule magnets (SMMs) have sparked great interest, but chiral
SMMs obtained via spontaneous resolution are rarely reported. We synthesized a series of …

Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances

J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …

From dinuclear to two-dimensional Dy (iii) complexes: single crystal–single crystal transformation and single-molecule magnetic behavior

YS Jin, K Yu, N Zhang, YQ Zhang, CM Liu… - Journal of Materials …, 2023 - pubs.rsc.org
Regulating the magnetic properties through structural transformation and multifunctional
magnetic bistable materials attracts increasing interest in the research area of molecular …

Structure and Magnetism of LnIII2 (Ln= Gd, Tb, Dy, and Ho) Assemblies Constructed from a Bis (Hydrazone) Compartmental Ligand: Slow Magnetic Relaxation in the …

P Bhattacharya, R Bag, S Satpathi, SK Pati… - Crystal Growth & …, 2023 - ACS Publications
The aim of the paper was to synthesize a series of LnIII2 (Ln= Gd, Tb, Dy, and Ho)
complexes that offer a great perspective to construct functional magnetic materials. Here, we …

Recent progress for single-molecule magnets based on rare earth elements

X Yin, L Deng, L Ruan, Y Wu, F Luo, G Qin, X Han… - Materials, 2023 - mdpi.com
Single-molecule magnets (SMMs) have attracted much attention due to their potential
applications in molecular spintronic devices. Rare earth SMMs are considered to be the …

Influence of lattice water molecules on the magnetization dynamics of binuclear dysprosium (iii) compounds: insights from magnetic and ab initio calculations

J Du, S Wei, Z Jiang, H Ke, L Sun, Y Zhang… - Physical Chemistry …, 2023 - pubs.rsc.org
Lattice water effects on the structures and magnetic properties of single-molecule magnets
(SMMs) have attracted considerable attention. Herein, we have successfully synthesized two …

A tetracobalt (ii) cluster with a two vertex truncated dicubane topology endogenously supported by carboxylate-based (2-pyridyl) methylamine ligands: magneto …

S Kant, S Saha, F Lloret, J Cano, R Mukherjee - Dalton Transactions, 2023 - pubs.rsc.org
A reaction between CoCl2 and L3-(CO2−) 2 (2: 1 stoichiometry) in CH3OH affords a discrete
complex [CoII4-{L3-(CO2−) 2} 2 (μ3-OCH3) 2 (CH3OH) 2 (H2O) 2Cl2](1)[L3-(CO2−) 2= 3-[N …

Toroidal moment and dynamical control in luminescent 1D and 3D terbium calixarene compounds

H Wang, Z Zhu, L La Droitte, W Liao, O Cador… - Chemical …, 2023 - pubs.rsc.org
A toroidal moment can be generated spontaneously in inorganic (atom-based) ferrotoroidic
materials that breaks both time-reversal and space-inversion symmetries, attracting great …