Enantiomers, where chirality arises from restricted rotation around a single bond, are
atropisomers. Due to the unique nature of the origins of their chirality, synthetic strategies to …

In recent years, the silver‐catalyzed and silver‐promoted isocyanide reactions have
attracted much attention, due to its efficiency in the formation of diverse new bonds and good …

The development of catalytic asymmetric reaction with water as the reactant is challenging
due to the reactivity‐and stereoselectivity‐control issues resulted from the low nucleophilicity …

We describe herein an intriguing method for the synthesis of biaryl aldehydes bearing both
axial and central chirality through a desymmetric [3+ 2] cycloaddition reaction of activated …

The development of efficient processes for the preparation of structurally diverse axially
chiral biaryls has been an important goal in synthetic organic chemistry and asymmetric …

Herein, we report that under mild and transition-metal-free conditions an unprecedented and
practical SN2′ reaction of Morita–Baylis–Hillman adducts with isocyanoacetates takes …

An organocatalytic asymmetric synthesis of directly linked benzothiazole‐dihydroimidazoles
with two adjacent tertiary‐quaternary stereocenters through a Mannich‐type reaction of …

Isothiazole units exist in many natural products and pharmaceutics. Up to now, construction
of isothiazole‐containing axially chiral biaryls has not been reported yet. Herein we disclose …

This chapter discusses the five-membered ring systems with O & N atoms such as
isoxazoles, isoxazolines, isoxazolidines, oxazoles, oxazolines, oxazolidines, and …