Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties

J Li, M Gao, W Yan, J Yu - Chemical Science, 2023 - pubs.rsc.org
Zeolites are typically a class of crystalline microporous aluminosilicates that are constructed
by SiO4 and AlO4 tetrahedra. Because of their unique porous structures, strong Brönsted …

Intergrowth zeolites, synthesis, characterization, and catalysis

Y Wang, C Tong, Q Liu, R Han, C Liu - Chemical Reviews, 2023 - ACS Publications
Microporous zeolites that can act as heterogeneous catalysts have continued to attract a
great deal of academic and industrial interest, but current progress in their synthesis and …

Machine learning-assisted crystal engineering of a zeolite

X Li, H Han, N Evangelou, NJ Wichrowski, P Lu… - Nature …, 2023 - nature.com
It is shown that Machine Learning (ML) algorithms can usefully capture the effect of
crystallization composition and conditions (inputs) on key microstructural characteristics …

Synthesis strategies to control the Al distribution in zeolites: thermodynamic and kinetic aspects

J Bae, M Dusselier - Chemical Communications, 2023 - pubs.rsc.org
The activity and selectivity of acid-catalyzed chemistry is highly dependent on the Brønsted
and Lewis acid sites generated by Al substitutions in a zeolite framework with the desired …

High-throughput phase elucidation of polycrystalline materials using serial rotation electron diffraction

Y Luo, B Wang, S Smeets, J Sun, W Yang, X Zou - Nature Chemistry, 2023 - nature.com
Rapid phase elucidation of polycrystalline materials is essential for developing new
materials of chemical, pharmaceutical and industrial interest. Yet, the size and quantity of …

Approaching enzymatic catalysis with zeolites or how to select one reaction mechanism competing with others

P Ferri, C Li, D Schwalbe-Koda, M Xie… - Nature …, 2023 - nature.com
Approaching the level of molecular recognition of enzymes with solid catalysts is a
challenging goal, achieved in this work for the competing transalkylation and …

Catching a New Zeolite as a Transition Material during Deconstruction

Q Yue, G Steciuk, M Mazur, J Zhang… - Journal of the …, 2023 - ACS Publications
Zeolites are key materials in both basic research and industrial applications. However, their
synthesis is neither diverse nor applicable to labile frameworks because classical …

Recent progress in novel zeolite catalysts for selective catalytic reduction of nitrogen oxides

A Guo, H Liu, Y Li, Y Luo, D Ye, J Jiang, P Chen - Catalysis Today, 2023 - Elsevier
Selective catalytic reduction (SCR) using zeolite catalysts is a key technology for the
abatement of nitrogen oxides (NO x) from lean-burn heavy-duty vehicles. With the increasing …

Atomic Imaging of Zeolites and Confined Single Molecules by iDPC-STEM

H Xiong, H Wang, X Chen, F Wei - ACS Catalysis, 2023 - ACS Publications
Zeolites are a family of nanoporous crystalline materials with ordered channel systems,
flexibly adjustable activity, and high hydrothermal stability and have been widely used as …