Spin hyperpolarization in modern magnetic resonance
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …
disciplines and in various practical applications, with medical magnetic resonance imaging …
Polarizing agents for efficient high field DNP solid-state NMR spectroscopy under magic-angle spinning: from design principles to formulation strategies
G Menzildjian, J Schlagnitweit, G Casano, O Ouari… - Chemical …, 2023 - pubs.rsc.org
Dynamic Nuclear Polarization (DNP) has recently emerged as a cornerstone approach to
enhance the sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning (MAS) …
enhance the sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning (MAS) …
PyrroTriPol: a semi-rigid trityl-nitroxide for high field dynamic nuclear polarization
Magic angle spinning (MAS) dynamic nuclear polarization (DNP) has significantly
broadened the scope of solid-state NMR to study biomolecular systems and materials. In …
broadened the scope of solid-state NMR to study biomolecular systems and materials. In …
The effect of disorder on endogenous MAS-DNP: Study of silicate glasses and crystals
B Thomas, D Jardón-Álvarez, R Carmieli… - The Journal of …, 2023 - ACS Publications
In dynamic nuclear polarization nuclear magnetic resonance (DNP-NMR) experiments, the
large Boltzmann polarization of unpaired electrons is transferred to surrounding nuclei …
large Boltzmann polarization of unpaired electrons is transferred to surrounding nuclei …
Design of a cryogen-free high field dual EPR and DNP probe
We present the design and construction of a cryogen free, dual electron paramagnetic
resonance (EPR) and nuclear magnetic resonance (NMR) probe for novel dynamic nuclear …
resonance (EPR) and nuclear magnetic resonance (NMR) probe for novel dynamic nuclear …
Fast magic angle spinning for the characterization of milligram quantities of organic and biological solids at natural isotopic abundance by 13C–13C correlation DNP …
AN Smith, R Harrabi, T Halbritter, D Lee… - Solid state nuclear …, 2023 - Elsevier
We show that multidimensional solid-state NMR 13 C–13 C correlation spectra of
biomolecular assemblies and microcrystalline organic molecules can be acquired at natural …
biomolecular assemblies and microcrystalline organic molecules can be acquired at natural …
Metal ions based dynamic nuclear polarization: MI-DNP
D Jardón-Álvarez, M Leskes - Progress in Nuclear Magnetic Resonance …, 2023 - Elsevier
Over the last two decades magic angle spinning dynamic nuclear polarization (MAS DNP)
has revolutionized NMR for materials characterization, tackling its main limitation of …
has revolutionized NMR for materials characterization, tackling its main limitation of …
[HTML][HTML] A primer to polarizing agent design: Quantum mechanical understanding of cross effect magic-angle spinning dynamic nuclear polarization
Abstract Dynamic Nuclear Polarization (DNP) is transforming the landscape of solid-state
characterization for both biological solids and functional materials. By transferring electron …
characterization for both biological solids and functional materials. By transferring electron …
Dynamic nuclear polarization in inorganic solids from paramagnetic metal ion dopants
D Jardón-Álvarez, M Leskes - … Chemistry III, Third …, 2023 - weizmann.elsevierpure.com
In this chapter, an introduction to dynamic nuclear polarization (DNP) solid state nuclear
magnetic resonance (NMR) is given. The main focus lies in presenting the use of …
magnetic resonance (NMR) is given. The main focus lies in presenting the use of …
An analytical treatment of electron spectral saturation for dynamic nuclear polarization NMR of rotating solids
Z Gan - The Journal of Chemical Physics, 2023 - pubs.aip.org
Saturation of electron magnetization by microwave irradiation under magic-angle spinning
(MAS) is studied theoretically. The saturation is essential for dynamic nuclear polarization …
(MAS) is studied theoretically. The saturation is essential for dynamic nuclear polarization …