Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes
AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …
been actively studied for potential applications in the new generation of high-density data …
Modulation of the Slow Relaxation of the Magnetization Dynamics through Second Coordination Sphere in Macrocyclic Dysprosium (III) Complexes
E Rotondo, M Aragon-Alberti, J Rouquette… - Crystal Growth & …, 2024 - ACS Publications
Single-molecule magnets (SMMs) exhibit unique magnetic properties related to the
molecular nature of these “isolated” coordination complexes. In this study, we investigate the …
molecular nature of these “isolated” coordination complexes. In this study, we investigate the …
Organolanthanide Single‐Molecule Magnets with Heterocyclic Ligands
Y Wang, QC Luo, YZ Zheng - … Chemie International Edition, 2024 - Wiley Online Library
Lanthanide (Ln) based mononuclear single‐molecule magnets (SMMs) provide probably
the finest ligand regulation model for magnetic property. Recently, the development of such …
the finest ligand regulation model for magnetic property. Recently, the development of such …
Synthesis, characterization and magnetic properties of halogenated tetranuclear cubane-like nickel (ii) complexes
M Aryaeifar, HA Rudbari, E Moreno-Pineda… - New Journal of …, 2024 - pubs.rsc.org
Four Ni4O4 cubanes with formula [Ni4 (Cl2-L) 4 (μ3-OMe) 4 (MeOH) 4](1),[Ni4 (Br2-L) 4 (μ3-
OMe) 4 (MeOH) 4](2),[Ni4 (I2-L) 4 (μ3-OMe) 4 (MeOH) 4](3) and [Ni4 (BrCl-L) 4 (μ3-OMe) 4 …
OMe) 4 (MeOH) 4](2),[Ni4 (I2-L) 4 (μ3-OMe) 4 (MeOH) 4](3) and [Ni4 (BrCl-L) 4 (μ3-OMe) 4 …
Electronic Structure of Three-Coordinate FeII and CoII β-Diketiminate Complexes
AL Nagelski, M Ozerov, MS Fataftah… - Inorganic …, 2024 - ACS Publications
The β-diketiminate supporting group,[ArNCRCHCRNAr]−, stabilizes low coordination
number complexes. Four such complexes, where R= tert-butyl, Ar= 2, 6-diisopropylphenyl …
number complexes. Four such complexes, where R= tert-butyl, Ar= 2, 6-diisopropylphenyl …
On‐Surface Synthesis of Organolanthanide Sandwich Complexes
The synthesis of lanthanide‐based organometallic sandwich compounds is very appealing
regarding their potential for single‐molecule magnetism. Here, it is exploited by on‐surface …
regarding their potential for single‐molecule magnetism. Here, it is exploited by on‐surface …
Constructing high axiality mononuclear dysprosium molecular magnets via a regulation-of-co-ligands strategy
JL Wang, JT Chen, H Yan, TT Wang, YQ Zhang… - Dalton …, 2024 - pubs.rsc.org
Two lanthanide complexes with formulae [DyIII (LN5)(pentafluoro-PhO) 3](1) and [DyIII
(LN5)(2, 6-difluoro-PhO) 2](BPh4)(2)(LN5= 2, 14-dimethyl-3, 6, 10, 13, 19-pentaazabicyclo …
(LN5)(2, 6-difluoro-PhO) 2](BPh4)(2)(LN5= 2, 14-dimethyl-3, 6, 10, 13, 19-pentaazabicyclo …
Eight-Coordinate Mono-and Dinuclear Dy (III) Complexes Containing a Rigid Equatorial Plane and an Anisobidentate Carboxylate Ligand in the Axial position …
A rigid pentadentate chelating ligand (H2L) has been utilized to synthesize a series of octa-
coordinate mononuclear complexes,[Dy (L)(Ph3PO)(OOCR)](where R= C6H5 (1), C (CH3) 3 …
coordinate mononuclear complexes,[Dy (L)(Ph3PO)(OOCR)](where R= C6H5 (1), C (CH3) 3 …
A serial of cyanide-bridged CrIII/ICuII complexes from 0D cluster to 2D network: Synthesis, crystal structure and magnetic property
S Meng, Z Xu, T Cao, Y Xin, Y Chen, C Wang… - Journal of Molecular …, 2024 - Elsevier
One cyanide-bridged heterometallic achiral complex and two pairs of enantiomers {[Cu
(Chxn) 2 Cr (bpb)(CN) 2] ClO 4}· CH 3 OH· H 2 O (1),{[Cu (S, S/R, R-Chxn) 2 Cr (CN) 5 (NO)] …
(Chxn) 2 Cr (bpb)(CN) 2] ClO 4}· CH 3 OH· H 2 O (1),{[Cu (S, S/R, R-Chxn) 2 Cr (CN) 5 (NO)] …
Exchange Couplings and Magneto‐Structural Correlations of Trinuclear MII‐UIV‐MII (MII=Co, Ni, Cu) Complexes
L Belkhiri, R Maurice, B Le Guennic… - European Journal of …, 2024 - Wiley Online Library
The magnetic properties of the trinuclear Schiff base complexes M2UL7 (MII= Co, Ni, Cu;
L7= N, N'‐bis (3‐hydroxysalicylidene)‐2, 2‐dimethyl‐1, 3‐propanediamine), exhibiting the …
L7= N, N'‐bis (3‐hydroxysalicylidene)‐2, 2‐dimethyl‐1, 3‐propanediamine), exhibiting the …