Organocatalytic Atroposelective Dynamic Kinetic Resolution Involving Ring Manipulations

Q Shi, F Fang, DJ Cheng - Advanced Synthesis & Catalysis, 2024 - Wiley Online Library
Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …

Development of Configurationally Labile Biaryl Reagents for Atropisomer Synthesis

C Wu, Y Jin, X Zhang, R Gao… - European Journal of …, 2024 - Wiley Online Library
Axially chiral biaryl scaffolds are important in pharmaceuticals, natural products, and
asymmetric synthesis. Atroposelective ring‐opening of configurationally labile biaryl …

Catalytic stereodivergent and simultaneous construction of axial and point chirality

WT Wang, S Zhang, W Lin, ZH Luo, D Hu… - Organic Chemistry …, 2024 - pubs.rsc.org
Atropisomers possessing additional stereogenic centres have found wide applications in
various fields; however, the development of catalytic asymmetric reactions for their …

Palladium‐Catalyzed Allylation of Isocyanoacetates with Vinyl‐Aziridines

S Yan, ZJ Yu, ZK Guo, J Zhang… - European Journal of …, 2024 - Wiley Online Library
The first palladium‐catalyzed allylation of isocyanoacetates with vinyl aziridines has been
developed. The reaction conditions were suitable for a variety of α‐aryl isocyanoacetates as …