Understanding ligand-protected noble metal nanoclusters at work
MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …
Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters
Abstract Ultrasmall (< 2 nm) ligand-protected metal nanoclusters (NCs) have been an
emerging class of functional materials with rich coordination chemistry, finding increasing …
emerging class of functional materials with rich coordination chemistry, finding increasing …
Engineering functional metal materials at the atomic level
With continuous research efforts devoted into synthesis and characterization chemistry of
functional nanomaterials in the past decades, the development of metal materials is …
functional nanomaterials in the past decades, the development of metal materials is …
Electrospray ionization mass spectrometry: A powerful platform for noble‐metal nanocluster analysis
T Chen, Q Yao, RR Nasaruddin… - Angewandte Chemie …, 2019 - Wiley Online Library
Electrospray ionization mass spectrometry (ESI‐MS) is an analytical technique that
measures the mass of a sample through “soft” ionization. Recent years have witnessed a …
measures the mass of a sample through “soft” ionization. Recent years have witnessed a …
Ion mobility–mass spectrometry of supramolecular complexes and assemblies
E Kalenius, M Groessl, K Rissanen - Nature Reviews Chemistry, 2019 - nature.com
Despite their structural and functional differences, synthetic supramolecular assemblies
share many similarities with biological assemblies, especially enzymes. The assemblies can …
share many similarities with biological assemblies, especially enzymes. The assemblies can …
Experimental Confirmation of a Topological Isomer of the Ubiquitous Au25(SR)18 Cluster in the Gas Phase
E Kalenius, S Malola, MF Matus, R Kazan… - Journal of the …, 2021 - ACS Publications
High-resolution electrospray ionization ion mobility mass spectrometry has revealed a gas-
phase isomer of the ubiquitous, extremely well-studied Au25 (SR) 18 cluster both in anionic …
phase isomer of the ubiquitous, extremely well-studied Au25 (SR) 18 cluster both in anionic …
A thirty-fold photoluminescence enhancement induced by secondary ligands in monolayer protected silver clusters
In this paper, we demonstrate that systematic replacement of the secondary ligand PPh3
leads to an enhancement in the near-infrared (NIR) photoluminescence (PL) of [Ag29 (BDT) …
leads to an enhancement in the near-infrared (NIR) photoluminescence (PL) of [Ag29 (BDT) …
Assembling atomically precise noble metal nanoclusters using supramolecular interactions
Supramolecular chemistry (SC) of noble metal nanoclusters (NMNCs) is one of the
fascinating areas of contemporary materials science. It is principally concerned with the …
fascinating areas of contemporary materials science. It is principally concerned with the …
The emergence of mass spectrometry for characterizing nanomaterials. Atomically precise nanoclusters and beyond
C Comby-Zerbino, X Dagany, F Chirot, P Dugourd… - Materials …, 2021 - pubs.rsc.org
Mass spectrometry (MS) is widely used in molecular science, and is now emerging as a
characterization technique for ultra-small nanoparticles. In the field of atomically precise …
characterization technique for ultra-small nanoparticles. In the field of atomically precise …
A concise guide to chemical reactions of atomically precise noble metal nanoclusters
Nanoparticles (NPs) with atomic precision, known as nanoclusters (NCs), are an emerging
field in materials science in view of their fascinating structure–property relationships …
field in materials science in view of their fascinating structure–property relationships …