Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures

XZ Li, CB Tian, QF Sun - Chemical Reviews, 2022 - ACS Publications
Lanthanide supramolecular chemistry is a fast growing and intriguing research field due to
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …

[HTML][HTML] Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

A ferrotoroidic candidate with well‐separated spin chains

J Zhang, X Wang, L Zhou, G Liu, DT Adroja… - Advanced …, 2022 - Wiley Online Library
The search of novel quasi‐1D materials is one of the important aspects in the field of
material science. Toroidal moment, the order parameter of ferrotoroidic order, can be …

Molecular magnetism of lanthanide: Advances and perspectives

Z Zhu, M Guo, XL Li, J Tang - Coordination Chemistry Reviews, 2019 - Elsevier
The discovery of the first example of lanthanide-based single molecule magnets (Ln-SMMs),
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …

[HTML][HTML] An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature

SK Gupta, T Rajeshkumar, G Rajaraman… - Chemical …, 2016 - pubs.rsc.org
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Magnetic relaxation pathways in lanthanide single-molecule magnets

RJ Blagg, L Ungur, F Tuna, J Speak, P Comar… - Nature …, 2013 - nature.com
Single-molecule magnets are compounds that exhibit magnetic bistability caused by an
energy barrier for the reversal of magnetization (relaxation). Lanthanide compounds are …

Main group chemistry at the interface with molecular magnetism

FS Guo, AK Bar, RA Layfield - Chemical reviews, 2019 - ACS Publications
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …