Biocatalytic site-selective (regioselective) organic transformations have been practiced for
decades, but the traditional limitations of enzymes regarding narrow substrate acceptance …

The selective functionalization of C (sp 3)–H bonds via intramolecular amination reactions
represents a very attractive strategy for the construction of saturated N-containing …

Expanding the reaction scope of natural metalloenzymes can provide new opportunities for
biocatalysis. Mononuclear non‐heme iron‐dependent enzymes represent a large class of …

Expanding Nature's catalytic repertoire to include reactions important in synthetic chemistry
opens new opportunities for biocatalysis. An intramolecular C–H amination route to …

The use of rate‐accelerating variants of P450Bm3 coupled with decoy molecules is
described, resulting in improved catalytic activity for hydroxylation and epoxidation …