Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Recent trends in advanced photoinitiators for vat photopolymerization 3D printing

Y Bao - Macromolecular rapid communications, 2022 - Wiley Online Library
Abstract 3D printing has revolutionized the way of manufacturing with a huge impact on
various fields, in particular biomedicine. Vat photopolymerization‐based 3D printing …

Degradable and recyclable polymers by reversible deactivation radical polymerization

MR Martinez, K Matyjaszewski - CCS Chemistry, 2022 - chinesechemsoc.org
Reversible deactivation radical polymerization (RDRP) provides unprecedented control over
polymer composition, size, functionality, and topology. Various materials, such as linear …

Ultrafast visible-light-induced ATRP in aqueous media with carbon quantum dots as the catalyst and its application for 3D printing

L Qiao, M Zhou, G Shi, Z Cui, X Zhang… - Journal of the …, 2022 - ACS Publications
Photoinduced atom transfer radical polymerization (ATRP) has been proved to be a versatile
technique for polymer network formation. However, the slow polymerization rates of typical …

Photo‐RAFT Polymerization for Hydrogel Synthesis through Barriers and Development of Light‐Regulated Healable Hydrogels under NIR Irradiation

Z Wu, T Zhang, X Shi, N Corrigan, G Ng… - Angewandte …, 2023 - Wiley Online Library
We report an aqueous and near‐infrared (NIR) light mediated photoinduced reversible
addition–fragmentation chain transfer (photo‐RAFT) polymerization system catalyzed by …

Near‐Infrared Light‐Induced Reversible Deactivation Radical Polymerization: Expanding Frontiers in Photopolymerization

Z Wu, C Boyer - Advanced Science, 2023 - Wiley Online Library
Photoinduced reversible deactivation radical polymerization (photo‐RDRP) or photoinduced
controlled/living radical polymerization has emerged as a versatile and powerful technique …

The emergence of reversible–deactivation radical polymerization in 3D printing

VA Bobrin, J Zhang, N Corrigan… - Advanced Materials …, 2023 - Wiley Online Library
The majority of materials 3D printed using vat photopolymerization techniques are prepared
by uncontrolled polymerization methods and cannot be easily modified to introduce …

Covalent adaptable microstructures via combining two‐photon laser printing and alkoxyamine chemistry: toward living 3D microstructures

Y Jia, CA Spiegel, A Welle, S Heißler… - Advanced Functional …, 2023 - Wiley Online Library
Manufacturing programmable materials, whose mechanical properties can be adapted on
demand, is highly desired for their application in areas ranging from robotics, to …

A Porphyrin‐Based Organic Network Comprising Sustainable Carbon Dots for Photopolymerization

X Luo, J Wan, N Meckbach, V Strehmel… - Angewandte Chemie …, 2022 - Wiley Online Library
Sustainable carbon dots (CDs) based on furfuraldehyde (F‐CD) resulted in a photosensitive
material after pursuing the Alder‐Longo reaction. The porphyrin moiety formed connects the …

Application of RAFT in 3D printing: where are the future opportunities?

A Bagheri - Macromolecules, 2023 - ACS Publications
Research into 3D printing using reversible addition–fragmentation chain transfer (RAFT)
polymerization has garnered interest since it was first reported in 2019. This technique was …