Reactive intermediates as recognized chemical entities date back for over a century, and
among the earliest examples were simple free radicals, as identified in 1879, when it was …

Highlights•Advances in the combination of the CuAAC reaction with direct screening.•Before
library assembly, the bioisosteric potential of 1, 2, 3-triazole should be confirmed.•The …

Metal–organic frameworks (MOFs) that contain open metal sites have the potential for
storing hydrogen (H2) at ambient temperatures. In particular, Cu (I)-based MOFs …

A visible-light-mediated photocatalyzed protocol utilizing copper–phenanthroline-based
catalysts has been developed that can convert a large number of olefins into their …

Different loadings of Cu single atoms were anchored on a graphitic carbon nitride (g-C3N4)
matrix using a two-step thermal synthesis method and applied in liquid-phase cyclohexene …

Inspired by the dynamic coordination and dissociation between metal ions and ligands
involved in biochemical reactions, we proposed and explored in detail a new electrochromic …

To obtain mechanistic insights into the inherent reactivity patterns for copper (I)–O2 adducts,
a new cupric–superoxo complex [(DMM-tmpa) CuII (O2•–)]+(2)[DMM-tmpa= tris ((4-methoxy …

Metal cations or complexes stabilized by neutral, nonaqueous ligands are important in
numerous synthetic processes, 1-3 and a large variety of such complexes incorporating …

With an anisole-containing polypyridylamine potential tetradentate ligand OL, a μ-1, 2-
peroxo-dicopper (II) complex [{OLCuII} 2 (O22−)] 2+ forms from the reaction of the …

The continued development of solar energy as a renewable resource necessitates new
approaches to sustaining photodriven charge separation (CS). We present a bioinspired …