Lanthanide single-molecule magnets
DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …
coordination compound could, at liquid-helium temperatures, retain magnetization for long …
Cluster-based single-molecule magnets
CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …
2005 but also including coverage of earlier work where necessary for understanding of …
Organometallic single-molecule magnets
RA Layfield - Organometallics, 2014 - ACS Publications
Single-molecule magnets (SMMs) display slow relaxation of the magnetization, purely of
molecular origin, in the absence of an applied magnetic field. This review summarizes the …
molecular origin, in the absence of an applied magnetic field. This review summarizes the …
Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians
C Rudowicz, M Karbowiak - Coordination Chemistry Reviews, 2015 - Elsevier
This review provides a summary of distinct Hamiltonians used to describe magnetic and
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …
Fine-Tuning the Single-Molecule Magnet Properties of a [Dy(III)-Radical]2 Pair
EM Fatila, M Rouzières, MC Jennings… - Journal of the …, 2013 - ACS Publications
A supramolecular species composed of a pair of nonequivalent Dy (III)–radical complexes
exhibits single-molecule magnet (SMM) properties. The weak effective antiferromagnetic …
exhibits single-molecule magnet (SMM) properties. The weak effective antiferromagnetic …
Single-Molecule Magnetism in Three Related {CoIII2DyIII2}-Acetylacetonate Complexes with Multiple Relaxation Mechanisms
SK Langley, NF Chilton, B Moubaraki… - Inorganic …, 2013 - ACS Publications
Three new heterometallic complexes with formulas of [DyIII2CoIII2 (OMe) 2 (teaH) 2 (acac) 4
(NO3) 2](1),[DyIII2CoIII2 (OH) 2 (teaH) 2 (acac) 4 (NO3) 2]· 4H2O (2), and [DyIII2CoIII2 …
(NO3) 2](1),[DyIII2CoIII2 (OH) 2 (teaH) 2 (acac) 4 (NO3) 2]· 4H2O (2), and [DyIII2CoIII2 …
Two dy (III) single-molecule magnets with their performance tuned by schiff base ligands
S Yu, Z Hu, Z Chen, B Li, YQ Zhang, Y Liang… - Inorganic …, 2019 - ACS Publications
To develop new lanthanide single-molecule magnets (SMMs), two new complexes of [Dy2
(MeOH) 2 (HL1) 2 (NO3) 2]· 2MeOH (1) and [Dy6 (μ3-OH) 2 (L2) 2 (HL2) 2 (H2L2) 2Cl2 …
(MeOH) 2 (HL1) 2 (NO3) 2]· 2MeOH (1) and [Dy6 (μ3-OH) 2 (L2) 2 (HL2) 2 (H2L2) 2Cl2 …
Attaining record-high magnetic exchange, magnetic anisotropy and blocking barriers in dilanthanofullerenes
S Dey, G Rajaraman - Chemical Science, 2021 - pubs.rsc.org
While the blocking barrier (Ueff) and blocking temperature (TB) for “Dysprocenium” SIMs
have been increased beyond liquid N2 temperature, device fabrication of these molecules …
have been increased beyond liquid N2 temperature, device fabrication of these molecules …
Influence of an Inner-Sphere K+ Ion on the Magnetic Behavior of N23– Radical-Bridged Dilanthanide Complexes Isolated Using an External Magnetic Field
The synthesis and full magnetic characterization of a new series of N23–radical-bridged
lanthanide complexes [{(R2N) 2 (THF) Ln} 2 (μ3-η2: η2: η2-N2) K][1-Ln; Ln= Gd, Tb, Dy; …
lanthanide complexes [{(R2N) 2 (THF) Ln} 2 (μ3-η2: η2: η2-N2) K][1-Ln; Ln= Gd, Tb, Dy; …
Designing a Dy2 Single-Molecule Magnet with Two Well-Differentiated Relaxation Processes by Using a Nonsymmetric Bis-bidentate Bipyrimidine-N-Oxide Ligand …
Herein we report a dinuclear [(μ-mbpymNO){(tmh) 3Dy} 2](1) single-molecule magnet (SMM)
showing two nonequivalent DyIII centers, which was rationally prepared from the reaction of …
showing two nonequivalent DyIII centers, which was rationally prepared from the reaction of …