Progress in Photoinduced Radical Reactions using Electron Donor‐Acceptor Complexes

L Zheng, L Cai, K Tao, Z Xie, YL Lai… - Asian Journal of …, 2021 - Wiley Online Library
Photocatalyzed organic synthesis transformation is a remarkable green synthetic strategy
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …

Recent progress of direct thiocyanation reactions

H Chen, X Shi, X Liu, L Zhao - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
Thiocyanates are common in natural products, synthetic drugs and bioactive molecules.
Many thiocyanate derivatives show excellent antibacterial, antiparasitic and anticancer …

Direct C–H sulfenylation of quinoxalinones with thiols under visible-light-induced photocatalyst-free conditions

QH Teng, Y Yao, WX Wei, HT Tang, JR Li, YM Pan - Green Chemistry, 2019 - pubs.rsc.org
A photocatalyst-free visible-light-promoted sulfenylation of quinoxalinones with thiols via
cross-dehydrogenative coupling was developed. This protocol allowed the direct formation …

Visible light-induced thiocyanation of enaminone C–H bond to access polyfunctionalized alkenes and thiocyano chromones

Y Gao, Y Liu, JP Wan - The Journal of Organic Chemistry, 2019 - ACS Publications
The visible light induced C–H bond thiocyanation on the α-site of tertiary enaminones has
been realized under metal-free, photocatalytic conditions in the presence of Rose Bengal …

Developments towards synthesis of N-heterocycles from amidines via C–N/C–C bond formation

W Guo, M Zhao, W Tan, L Zheng, K Tao… - Organic Chemistry …, 2019 - pubs.rsc.org
The synthesis of N-heterocycles is one of the most active areas due to their structures with
extensive applications in the fields of organic, pharmaceutical and materials chemistry. It is …

Charge Separation in Metal‐Organic Framework Enables Heterogeneous Thiol Catalysis

S Cheng, J Ouyang, M Li, Y Diao, J Yao… - Angewandte Chemie …, 2023 - Wiley Online Library
Photoinduced metal–organic framework (MOF) enabled heterogeneous thiol catalysis has
been achieved for the first time. MOF Zr‐TPDCS‐1, consisting of Zr6‐clusters and TPDCS …

Recent advances in photocatalytic C–S/P–S bond formation via the generation of sulfur centered radicals and functionalization

W Guo, K Tao, W Tan, M Zhao, L Zheng… - Organic Chemistry …, 2019 - pubs.rsc.org
Thioyl and sulfonyl radicals are usually produced from various thiols and sulfonyl derivatives
in high efficiency by single-electron-transfer (SET) oxidation. The generated sulfur …

Design and Use of Electrophilic Thiocyanating and Selenocyanating Reagents: An Interesting Trend for the Construction of SCN‐and SeCN‐Containing Compounds

M Gao, M Vuagnat, MY Chen… - … A European Journal, 2021 - Wiley Online Library
Organothiocyanate and organoselenocyanate compounds are of paramount importance in
organic chemistry as they are key intermediates to access sulfur‐and selenium‐containing …

A general photo-induced wide-scope regioselective hydroboration of alkenes without using a photocatalyst or an external initiator

YQ Miao, XY Li, QJ Pan, Y Ma, JX Kang, YN Ma… - Green …, 2022 - pubs.rsc.org
Despite the recent development of boryl radical reactions, current methods to generate them
by relying on photocatalysts or radical initiators cause contamination of the reaction. Herein …

Site-selective electrochemical thiocyanation of benzylic C–H bonds

D Liu, Z Zhang, J Yu, H Chen, X Lin, M Li… - Organic Chemistry …, 2022 - pubs.rsc.org
Direct benzylic C (sp3)–H thiocyanation is explored as a straightforward strategy toward the
synthesis of thiocyanate derivatives. We report herein an electrochemical protocol for site …