Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Abstraction of a chloride ligand from the dysprosium metallocene [(Cpttt) 2DyCl](1Dy Cpttt=
1, 2, 4‐tri (tert‐butyl) cyclopentadienide) by the triethylsilylium cation produces the first base …

The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

Conspectus The discovery of materials capable of storing magnetic information at the level
of single molecules and even single atoms has fueled renewed interest in the slow magnetic …

Abstract Luminescent lanthanide-based Single-Molecule Magnets (SMM) are multifunctional
molecule-based materials that combine luminescence and magnetic properties in the same …

Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Due to the heterometallic synergistic effects from different metals, heterometallic clusters are
of great importance in small-molecule activation and catalysis. For example, both biological …