Defect Engineering of MOF‐Based Membrane for Gas Separation

S Li, W Han, QF An, KT Yong… - Advanced Functional …, 2023 - Wiley Online Library
Metal–organic frameworks (MOFs) are highly versatile materials that have been identified as
promising candidates for membrane‐based gas separation applications due to their …

pH-stable MOFs: Design principles and applications

B Pramanik, R Sahoo, MC Das - Coordination Chemistry Reviews, 2023 - Elsevier
Metal–organic frameworks (MOFs) have been attracting tremendous attention and
recognized as one of the most promising porous materials due to their great structural …

Kilogram-Scale Fabrication of a Robust Olefin-Linked Covalent Organic Framework for Separating Ethylene from a Ternary C2 Hydrocarbon Mixture

Z Wang, Y Zhang, E Lin, S Geng, M Wang… - Journal of the …, 2023 - ACS Publications
One-step adsorptive purification of ethylene (C2H4) from a ternary mixture of acetylene
(C2H2), C2H4, and ethane (C2H6) by a single material is of great importance but …

Near‐ and Long‐Range Electronic Modulation of Single Metal Sites to Boost CO2 Electrocatalytic Reduction

C Hu, Y Zhang, A Hu, Y Wang, X Wei… - Advanced …, 2023 - Wiley Online Library
Tuning the electronic structure of the active center is effective to improve the intrinsic activity
of single‐atom catalysts but the realization of precise regulation remains challenging …

A general large-scale synthesis approach for crystalline porous materials

X Liu, A Wang, C Wang, J Li, Z Zhang… - Nature …, 2023 - nature.com
Crystalline porous materials such as covalent organic frameworks (COFs), metal-organic
frameworks (MOFs) and porous organic cages (POCs) have been widely applied in various …

New‐Generation Anion‐Pillared Metal–Organic Frameworks with Customized Cages for Highly Efficient CO2 Capture

Y Hu, Y Jiang, J Li, L Wang, M Steiner… - Advanced Functional …, 2023 - Wiley Online Library
The rational design of porous materials for CO2 capture under realistic process conditions is
highly desirable. However, trade‐offs exist among a nanopore's capacity, selectivity …

Tetranuclear CuII Cluster as the Ten Node Building Unit for the Construction of a Metal–Organic Framework for Efficient C2H2/CO2 Separation

F Xiang, H Zhang, Y Yang, L Li, Z Que… - Angewandte Chemie …, 2023 - Wiley Online Library
Rational design of high nuclear copper cluster‐based metal–organic frameworks has not
been established yet. Herein, we report a novel MOF (FJU‐112) with the ten‐connected …

Fluorescence Enhancement of a Metal‐Organic Framework for Ultra‐Efficient Detection of Trace Benzene Vapor

WB Li, Y Wu, XF Zhong, XH Chen, G Liang… - Angewandte …, 2023 - Wiley Online Library
Indoor detection of volatile organic compounds (VOCs) concentration is necessary due to
the serious toxicity hazards even at trace level. However, physisorbents usually exhibit weak …

Selectivity Control in the Direct CO Esterification over Pd@ UiO‐66: The Pd Location Matters

S Hu, C Xie, YP Xu, X Chen, ML Gao… - Angewandte …, 2023 - Wiley Online Library
The selectivity control of Pd nanoparticles (NPs) in the direct CO esterification with methyl
nitrite toward dimethyl oxalate (DMO) or dimethyl carbonate (DMC) remains a grand …

Hybrid MOF Template‐Directed Construction of Hollow‐Structured In2O3@ZrO2 Heterostructure for Enhancing Hydrogenation of CO2 to Methanol

WG Cui, Q Zhang, L Zhou, ZC Wei, L Yu, JJ Dai… - Small, 2023 - Wiley Online Library
Direct hydrogenation of CO2 to methanol using green hydrogen has emerged as a
promising method for carbon neutrality, but qualifying catalysts represent a grand challenge …