Conjugate addition is among the most important synthetic protocols for constructing carbon
skeletons and is widely used to synthesize natural products and drugs. However …

A cobalt‐catalyzed decarboxylative Negishi coupling reaction of redox‐active aliphatic
esters with organozinc reagents was developed. The method enabled efficient alkyl–aryl …

Reactions involving alkenyl acetates offer cost-effective and environmentally friendly routes
for alkene synthesis, yet their asymmetric variant remains elusive. Concurrently, asymmetric …

Herein, we report the nickel-catalyzed denitrogenative cyclization reaction of 1, 2, 3, 4-
benzothiatriazine-1, 1-dioxides with arynes to generate the polysubstituted biaryl sultams …

A Co‐catalyzed effective transfer hydrogenation of various α‐ketoesters and N‐
cyclicsulfonylimides by safe and environmentally benign H2O as hydrogen source is …

The Co-catalyzed reactions of 2-halobenzamides and alkynes to form isoquinolones or 2-
vinyl benzamides are described here. The formation of the two selective products can be …

Nickel/photoredox catalysis has emerged as a powerful platform for exploring nontraditional
and challenging cross-couplings. Herein, a metallaphotoredox catalytic protocol has been …

Vinylsilanes were directly prepared from the corresponding vinyl triflates under magnesium-
promoted reductive conditions in THF with no transition metal catalyst, and gem-bis-silylated …

A denitrogenative palladium-catalyzed C (sp 2)–C (sp 2) cross-coupling of aryl-substituted
diazenes capped with a trimethylsilyl group and functionalized aryl bromides is reported. A …

The ortho C− H methylation and ipso C− O alkenylation of aryl triflates was regio‐selectively
achieved in one pot by palladium/norbornene (NBE) synergistic catalysis. This work …