Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

A brief history of OLEDs—emitter development and industry milestones

G Hong, X Gan, C Leonhardt, Z Zhang… - Advanced …, 2021 - Wiley Online Library
Organic light‐emitting diodes (OLEDs) have come a long way ever since their first
introduction in 1987 at Eastman Kodak. Today, OLEDs are especially valued in the display …

Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical …

H Amouri - Chemical Reviews, 2022 - ACS Publications
The employment of N-heterocyclic carbenes (NHCs) to design luminescent metal
compounds has been the focus of recent intense investigations because of the strong σ …

Luminescent first-row transition metal complexes

C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …

Eliminating nonradiative decay in Cu (I) emitters:> 99% quantum efficiency and microsecond lifetime

R Hamze, JL Peltier, D Sylvinson, M Jung, J Cardenas… - Science, 2019 - science.org
Luminescent complexes of heavy metals such as iridium, platinum, and ruthenium play an
important role in photocatalysis and energy conversion applications as well as organic light …

Spin-vibronic mechanism for intersystem crossing

TJ Penfold, E Gindensperger, C Daniel… - Chemical …, 2018 - ACS Publications
Intersystem crossing (ISC), formally forbidden within nonrelativistic quantum theory, is the
mechanism by which a molecule changes its spin state. It plays an important role in the …

Photoactive complexes with earth-abundant metals

OS Wenger - Journal of the American Chemical Society, 2018 - ACS Publications
In this invited Perspective, recent developments and possible future directions of research
on photoactive coordination compounds made from nonprecious transition metal elements …

Coinage-metal-based cyclic trinuclear complexes with metal–metal interactions: theories to experiments and structures to functions

J Zheng, Z Lu, K Wu, GH Ning, D Li - Chemical Reviews, 2020 - ACS Publications
Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …

Cyclic (alkyl)(amino) carbenes (CAACs): recent developments

M Melaimi, R Jazzar, M Soleilhavoup… - Angewandte Chemie …, 2017 - Wiley Online Library
Abstract Discovered in 2005, cyclic (alkyl)(amino) carbenes (CAACs) are among the most
nucleophilic (σ donating) and also electrophilic (π‐accepting) stable carbenes known to …

Cyclic (alkyl)-and (aryl)-(amino) carbene coinage metal complexes and their applications

R Jazzar, M Soleilhavoup, G Bertrand - Chemical reviews, 2020 - ACS Publications
Cyclic (alkyl)-and (aryl)-(amino) carbenes (CAACs and CAArCs) are stronger σ-donors and
π-acceptors than imidazol-2-ylidenes and imidazolidin-2-ylidenes, the well-known N …