The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks

Z Hu, Y Wang, D Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …

Crystal engineering of porous coordination networks for C3 hydrocarbon separation

MY Gao, BQ Song, D Sensharma, MJ Zaworotko - SmartMat, 2021 - Wiley Online Library
Abstract C3 hydrocarbons (HCs), especially propylene and propane, are high‐volume
products of the chemical industry as they are utilized for the production of fuels, polymers …

Bioinspired graphene oxide membranes with dual transport mechanisms for precise molecular separation

H Dou, M Xu, B Jiang, G Wen, L Zhao… - Advanced Functional …, 2019 - Wiley Online Library
The implementation of membrane technology to replace or combine with energy‐intensive
cryogenic distillation for precise separation of ethylene/ethane mixture proves an extremely …

Facile loading of Cu (I) in MIL-100 (Fe) through redox-active Fe (II) sites and remarkable propylene/propane separation performance

AR Kim, TU Yoon, EJ Kim, JW Yoon, SY Kim… - Chemical Engineering …, 2018 - Elsevier
A novel Cu (I) loading method, which includes the reduction of CuCl 2 to CuCl without an
external reducing agent and high-temperature calcination, was developed using the redox …

Copper (I), silver (I), and gold (I) ethylene complexes of fluorinated and boron-methylated bis-and tris (pyridyl) borate chelators

BT Watson, M Vanga, A Noonikara-Poyil… - Inorganic …, 2023 - ACS Publications
Bis-and tris-pyridyl borate ligands containing pyridyl donor arms, a methylated boron cap,
and a fluorine-lined coordination pocket have been prepared and utilized in coinage metal …

A Molecular Compound for Highly Selective Purification of Ethylene

A Noonikara‐Poyil, H Cui, AA Yakovenko… - Angewandte …, 2021 - Wiley Online Library
Purification of C2H4 from an C2H4/C2H6 mixture is one of the most challenging separation
processes, which is achieved mainly through energy‐intensive, cryogenic distillation in …

Overcoming Fundamental Limitations in Adsorbent Design: Alkene Adsorption by Non‐porous Copper (I) Complexes

D Parasar, AH Elashkar, AA Yakovenko… - Angewandte …, 2020 - Wiley Online Library
Purifying alkenes from alkanes requires cryogenic distillation. This consumes energy
equivalent to countries of ca. 5 million people. Replacing distillation with adsorption …

Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper (i) centers

GM Su, H Wang, BR Barnett, JR Long… - Chemical …, 2021 - pubs.rsc.org
Metal–organic frameworks are promising materials for applications such as gas capture,
separation, and storage, due to their ability to selectively adsorb small molecules. The metal …

Low Heat of Adsorption of Ethylene Achieved by Major Solid‐State Structural Rearrangement of a Discrete Copper (I) Complex

NB Jayaratna, MG Cowan, D Parasar… - Angewandte …, 2018 - Wiley Online Library
The trinuclear copper (I) pyrazolate complex [Cu3] rearranges to the dinuclear analogue
[Cu2⋅(C2H4) 2] when exposed to ethylene gas. Remarkably, the [Cu3]↔[Cu2⋅(C2H4) 2] …

Boron-embedded hydrolyzed PIM-1 carbon membranes for synergistic ethylene/ethane purification

KS Liao, S Japip, JY Lai, TS Chung - Journal of Membrane Science, 2017 - Elsevier
For the first time, boron embedded carbon membranes have shown superior C 2 H 4
permeability and C 2 H 4/C 2 H 6 selectivity to the upper bound line under both pure and …