The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …
Crystal engineering of porous coordination networks for C3 hydrocarbon separation
Abstract C3 hydrocarbons (HCs), especially propylene and propane, are high‐volume
products of the chemical industry as they are utilized for the production of fuels, polymers …
products of the chemical industry as they are utilized for the production of fuels, polymers …
Bioinspired graphene oxide membranes with dual transport mechanisms for precise molecular separation
The implementation of membrane technology to replace or combine with energy‐intensive
cryogenic distillation for precise separation of ethylene/ethane mixture proves an extremely …
cryogenic distillation for precise separation of ethylene/ethane mixture proves an extremely …
Facile loading of Cu (I) in MIL-100 (Fe) through redox-active Fe (II) sites and remarkable propylene/propane separation performance
A novel Cu (I) loading method, which includes the reduction of CuCl 2 to CuCl without an
external reducing agent and high-temperature calcination, was developed using the redox …
external reducing agent and high-temperature calcination, was developed using the redox …
Copper (I), silver (I), and gold (I) ethylene complexes of fluorinated and boron-methylated bis-and tris (pyridyl) borate chelators
Bis-and tris-pyridyl borate ligands containing pyridyl donor arms, a methylated boron cap,
and a fluorine-lined coordination pocket have been prepared and utilized in coinage metal …
and a fluorine-lined coordination pocket have been prepared and utilized in coinage metal …
A Molecular Compound for Highly Selective Purification of Ethylene
Purification of C2H4 from an C2H4/C2H6 mixture is one of the most challenging separation
processes, which is achieved mainly through energy‐intensive, cryogenic distillation in …
processes, which is achieved mainly through energy‐intensive, cryogenic distillation in …
Overcoming Fundamental Limitations in Adsorbent Design: Alkene Adsorption by Non‐porous Copper (I) Complexes
Purifying alkenes from alkanes requires cryogenic distillation. This consumes energy
equivalent to countries of ca. 5 million people. Replacing distillation with adsorption …
equivalent to countries of ca. 5 million people. Replacing distillation with adsorption …
Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper (i) centers
Metal–organic frameworks are promising materials for applications such as gas capture,
separation, and storage, due to their ability to selectively adsorb small molecules. The metal …
separation, and storage, due to their ability to selectively adsorb small molecules. The metal …
Low Heat of Adsorption of Ethylene Achieved by Major Solid‐State Structural Rearrangement of a Discrete Copper (I) Complex
The trinuclear copper (I) pyrazolate complex [Cu3] rearranges to the dinuclear analogue
[Cu2⋅(C2H4) 2] when exposed to ethylene gas. Remarkably, the [Cu3]↔[Cu2⋅(C2H4) 2] …
[Cu2⋅(C2H4) 2] when exposed to ethylene gas. Remarkably, the [Cu3]↔[Cu2⋅(C2H4) 2] …
Boron-embedded hydrolyzed PIM-1 carbon membranes for synergistic ethylene/ethane purification
For the first time, boron embedded carbon membranes have shown superior C 2 H 4
permeability and C 2 H 4/C 2 H 6 selectivity to the upper bound line under both pure and …
permeability and C 2 H 4/C 2 H 6 selectivity to the upper bound line under both pure and …