Boron‐Nitrogen Lewis Pairs in the Assembly of Supramolecular Macrocycles, Molecular Cages, Polymers, and 3D Materials
B Chen, F Jäkle - Angewandte Chemie, 2024 - Wiley Online Library
Covering an exceptionally wide range of bond strengths, the dynamic nature and facile
tunability of dative B− N bonds is highly attractive when it comes to the assembly of …
tunability of dative B− N bonds is highly attractive when it comes to the assembly of …
Diverse uses of the reaction of frustrated Lewis pair (FLP) with hydrogen
DW Stephan - Journal of the American Chemical Society, 2021 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs) emerged from the discovery
that H2 can be reversibly activated by combinations of sterically encumbered main group …
that H2 can be reversibly activated by combinations of sterically encumbered main group …
Polymer-supported Lewis acids and bases: Synthesis and applications
In the past decade the synthesis of novel stimuli-responsive materials has been driven by
the pursuit of new applications and, more recently, sustainable and reusable systems. Of …
the pursuit of new applications and, more recently, sustainable and reusable systems. Of …
Porous frustrated Lewis pair catalysts: Advances and perspective
Summary Frustrated Lewis pairs (FLPs), well known for the ability to activate small
molecules via the concerted action of Lewis acid and Lewis base, have inspired an ever …
molecules via the concerted action of Lewis acid and Lewis base, have inspired an ever …
Light-Induced Polymeric Frustrated Radical Pairs as Building Blocks for Materials and Photocatalysts
M Wang, M Shanmugam, EJL McInnes… - Journal of the …, 2023 - ACS Publications
Polymeric frustrated Lewis pairs, or poly (FLP) s, have served to bridge the gap between
functional polymer science and main group catalysis, pairing the uniqueness of sterically …
functional polymer science and main group catalysis, pairing the uniqueness of sterically …
Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs
Polymeric materials bearing Frustrated Lewis Pair (FLP) functionality are promising
candidates for use as heterogeneous catalysts and adaptive materials, but synthetic access …
candidates for use as heterogeneous catalysts and adaptive materials, but synthetic access …
Lewis pairs as highly tunable dynamic cross-links in transient polymer networks
F Vidal, J Gomezcoello, RA Lalancette… - Journal of the American …, 2019 - ACS Publications
Classical Lewis pairs (LPs) between unhindered electron-poor Lewis acids (LAs) and
electron-rich Lewis bases (LBs) present an overlooked motif with tremendous potential as …
electron-rich Lewis bases (LBs) present an overlooked motif with tremendous potential as …
Cyclic ether triggers for polymeric frustrated Lewis pair gels
Sterically hindered Lewis acid and base centers are unable to form Lewis adducts, instead
forming frustrated Lewis pairs (FLPs), where latent reactivity can be utilized for the activation …
forming frustrated Lewis pairs (FLPs), where latent reactivity can be utilized for the activation …
Activation of Small Molecules and Hydrogenation of CO2 Catalyzed by Frustrated Lewis Pairs
The chemistry of frustrated Lewis pair (FLP) is widely explored in the activation of small
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …
Controlling the aggregation and assembly of boron‐containing molecular and polymeric materials
D Shimoyama, F Jäkle - Aggregate, 2022 - Wiley Online Library
Boron‐containing molecules and polymers are attractive as powerful tunable Lewis acids for
small molecule activation and catalysis, as luminescent materials for organic electronic …
small molecule activation and catalysis, as luminescent materials for organic electronic …