Boron‐Nitrogen Lewis Pairs in the Assembly of Supramolecular Macrocycles, Molecular Cages, Polymers, and 3D Materials

B Chen, F Jäkle - Angewandte Chemie, 2024 - Wiley Online Library
Covering an exceptionally wide range of bond strengths, the dynamic nature and facile
tunability of dative B− N bonds is highly attractive when it comes to the assembly of …

Diverse uses of the reaction of frustrated Lewis pair (FLP) with hydrogen

DW Stephan - Journal of the American Chemical Society, 2021 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs) emerged from the discovery
that H2 can be reversibly activated by combinations of sterically encumbered main group …

Polymer-supported Lewis acids and bases: Synthesis and applications

U Yolsal, TAR Horton, M Wang, MP Shaver - Progress in Polymer Science, 2020 - Elsevier
In the past decade the synthesis of novel stimuli-responsive materials has been driven by
the pursuit of new applications and, more recently, sustainable and reusable systems. Of …

Porous frustrated Lewis pair catalysts: Advances and perspective

Y Zhang, PC Lan, K Martin, S Ma - Chem Catalysis, 2022 - cell.com
Summary Frustrated Lewis pairs (FLPs), well known for the ability to activate small
molecules via the concerted action of Lewis acid and Lewis base, have inspired an ever …

Light-Induced Polymeric Frustrated Radical Pairs as Building Blocks for Materials and Photocatalysts

M Wang, M Shanmugam, EJL McInnes… - Journal of the …, 2023 - ACS Publications
Polymeric frustrated Lewis pairs, or poly (FLP) s, have served to bridge the gap between
functional polymer science and main group catalysis, pairing the uniqueness of sterically …

Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs

EA Latif, JD Hilgar, NA Romero - Journal of the American …, 2024 - ACS Publications
Polymeric materials bearing Frustrated Lewis Pair (FLP) functionality are promising
candidates for use as heterogeneous catalysts and adaptive materials, but synthetic access …

Lewis pairs as highly tunable dynamic cross-links in transient polymer networks

F Vidal, J Gomezcoello, RA Lalancette… - Journal of the American …, 2019 - ACS Publications
Classical Lewis pairs (LPs) between unhindered electron-poor Lewis acids (LAs) and
electron-rich Lewis bases (LBs) present an overlooked motif with tremendous potential as …

Cyclic ether triggers for polymeric frustrated Lewis pair gels

U Yolsal, TAR Horton, M Wang… - Journal of the American …, 2021 - ACS Publications
Sterically hindered Lewis acid and base centers are unable to form Lewis adducts, instead
forming frustrated Lewis pairs (FLPs), where latent reactivity can be utilized for the activation …

Activation of Small Molecules and Hydrogenation of CO2 Catalyzed by Frustrated Lewis Pairs

R Pal, M Ghara, PK Chattaraj - Catalysts, 2022 - mdpi.com
The chemistry of frustrated Lewis pair (FLP) is widely explored in the activation of small
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …

Controlling the aggregation and assembly of boron‐containing molecular and polymeric materials

D Shimoyama, F Jäkle - Aggregate, 2022 - Wiley Online Library
Boron‐containing molecules and polymers are attractive as powerful tunable Lewis acids for
small molecule activation and catalysis, as luminescent materials for organic electronic …