Microporous magnets

P Dechambenoit, JR Long - Chemical Society Reviews, 2011 - pubs.rsc.org
Combining porosity and magnetic ordering in a single material presents a significant
challenge since magnetic exchange generally requires short bridges between the spin …

Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

[HTML][HTML] Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Development of Single‐Molecule Magnets

D Shao, XY Wang - Chinese Journal of Chemistry, 2020 - Wiley Online Library
Single‐molecule magnets (SMMs) are paramagnetic molecules that can be magnetized
below a certain temperature and have potential applications in high‐density information …

Multifunctionality in hybrid magnetic materials based on bimetallic oxalate complexes

M Clemente-León, E Coronado… - Chemical Society …, 2011 - pubs.rsc.org
Multifunctionality in hybrid magnetic materials based on bimetallic oxalate complexes -
Chemical Society Reviews (RSC Publishing) DOI:10.1039/C0CS00111B Royal Society of …

Symmetry-breaking structural phase transitions in spin crossover complexes

M Shatruk, H Phan, BA Chrisostomo… - Coordination Chemistry …, 2015 - Elsevier
We review spin-crossover (SCO) complexes of 3d transition metal ions that exhibit structural
phase transitions (SPTs) associated with changes in the space group symmetry. An analysis …

Topological motifs in cyanometallates: from building units to three-periodic frameworks

EV Alexandrov, AV Virovets, VA Blatov… - Chemical …, 2015 - ACS Publications
This review focuses on topological features of three-periodic (framework) p, d, and f metal
cyano complexes or cyanometallates, ie coordination compounds, where CN–ligands play …

Redox activity and two-step valence tautomerism in a family of dinuclear cobalt complexes with a spiroconjugated bis (dioxolene) ligand

KG Alley, G Poneti, PSD Robinson… - Journal of the …, 2013 - ACS Publications
A family of dinuclear cobalt complexes with bridging bis (dioxolene) ligands derived from 3,
3, 3′, 3′-tetramethyl-1, 1′-spirobis (indane-5, 5′, 6, 6′-tetrol)(spiroH4) and ancillary …

Multifunctional metal–organic frameworks based on redox-active rhenium octahedral clusters

YM Litvinova, YM Gayfulin, KA Kovalenko… - Inorganic …, 2018 - ACS Publications
The redox-active rhenium octahedral cluster unit [Re6Se8 (CN) 6] 4–was combined with
Gd3+ ions and dicarboxylate linkers in novel types of metal–organic frameworks (MOFs) that …

Dicyanometalate chemistry: A type of versatile building block for the construction of cyanide-bridged molecular architectures

S Wang, XH Ding, YH Li, W Huang - Coordination Chemistry Reviews, 2012 - Elsevier
Cyanide-bridged molecule-based magnetic materials with reduced dimensionality, such as
single-molecule magnets (SMMs) and single-chain magnets (SCMs), have attracted great …