Thiomolybdate clusters: from homogeneous catalysis to heterogenization and active sites

S Batool, M Langer, SN Myakala, M Heiland… - Advanced …, 2024 - Wiley Online Library
Thiomolybdates are molecular molybdenum‐sulfide clusters formed from Mo centers and
sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due …

Reversing Free‐Electron Transfer of MoS2+x Cocatalyst for Optimizing Antibonding‐Orbital Occupancy Enables High Photocatalytic H2 Evolution

D Gao, P Deng, J Zhang, L Zhang, X Wang… - Angewandte …, 2023 - Wiley Online Library
The interaction between a co‐catalyst and photocatalyst usually induces spontaneous free‐
electron transfer between them, but the effect and regulation of the transfer direction on the …

Unraveling and leveraging in situ surface amorphization for enhanced hydrogen evolution reaction in alkaline media

Q Fu, LW Wong, F Zheng, X Zheng, CS Tsang… - Nature …, 2023 - nature.com
Surface amorphization provides electrocatalysts with more active sites and flexibility.
However, there is still a lack of experimental observations and mechanistic explanations for …

Triggering the Channel‐Sulfur Sites in 1T′‐ReS2 Cocatalyst toward Splendid Photocatalytic Hydrogen Generation

J Xu, W Zhong, X Zhang, X Wang, X Hong, H Yu - Small, 2023 - Wiley Online Library
Electron density manipulation of active sites in cocatalysts is of great essential to realize the
optimal hydrogen adsorption/desorption behavior for constructing high‐efficient H2 …

Emerging Trends in Metal-Organic Framework (MOFs) Photocatalysts for Hydrogen Energy Using Water Splitting: A State-of-the-Art Review

L Jia, M Arain, A Ahmed, F Yikai, C Zhenda… - Journal of Industrial and …, 2023 - Elsevier
Various photocatalysts have been developed for photocatalytic water splitting—one of the
most important processes that produces dihydrogen as clean energy for fuel cells. The …

Surface anchoring of nickel sulfide clusters as active sites and cocatalysts for photocatalytic antibiotic degradation and bacterial inactivation

H Zhang, Y Liu, H Liu, J Yin, L Shi, H Tang - Journal of Colloid and Interface …, 2023 - Elsevier
Achieving photocatalytic antibiotic degradation and bacterial inactivation with high efficiency
remains a challenging mission to originate a clean environment. In this work, ultra-small NiS …

In-situ construction of Schottky junctions by highly dispersed Ni co-catalysts supported on mesoporous defective t-TiO2 for boosting photocatalytic H2 evolution

J Cao, B Luo, Y Zhang, J Li, L Ma, D Jing - Separation and Purification …, 2023 - Elsevier
Designing photocatalysts with interfacial design and defect engineering are crucial to
improved H 2-evolution efficiency of photocatalytic water splitting. Herein, mesoporous tablet …

Trigger selenium sites and stable multiphasic-engineered modulated BiFeO3/MoSe2-1T/2H photocatalyst for hydrogen peroxide production

K Xu, Y Zhu, J Qian, Y He, Y Liu, B Lu, S Tang… - Applied Catalysis B …, 2024 - Elsevier
Regulating electron density at active sites holds profound importance in the advancement of
highly efficient photocatalysts for hydrogen peroxide (H 2 O 2) production. In this study, a …

[HTML][HTML] Slurry co-hydroprocessing of Kraft lignin and pyrolysis oil over unsupported NiMoS catalyst: A strategy for char suppression

YW Cheah, R Intakul, MA Salam, J Sebastian… - Chemical Engineering …, 2023 - Elsevier
Pyrolysis oil (PO) assisted Kraft lignin (KL) liquefaction over an unsupported NiMoS catalyst
in a paraffin solvent was explored in this work. A paraffin solvent was used to represent …

Combining Highly Dispersed Amorphous MoS3 with Pt Nanodendrites as Robust Electrocatalysts for Hydrogen Evolution Reaction

K Guo, J Zheng, J Bao, Y Li, D Xu - Small, 2023 - Wiley Online Library
Surface modification of electrocatalysts to obtain new or improved electrocatalytic
performance is currently the main strategy for designing advanced nanocatalysts. In this …