Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges
IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds
Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …
revolutionized synthetic planning over the past few decades as the use of these directing …
[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
Palladium-catalyzed transformations of alkyl C–H bonds
This Review summarizes the advancements in Pd-catalyzed C (sp3)–H activation via
various redox manifolds, including Pd (0)/Pd (II), Pd (II)/Pd (IV), and Pd (II)/Pd (0). While few …
various redox manifolds, including Pd (0)/Pd (II), Pd (II)/Pd (IV), and Pd (II)/Pd (0). While few …
Complementary Strategies for Directed C(sp3)−H Functionalization: A Comparison of Transition‐Metal‐Catalyzed Activation, Hydrogen Atom Transfer, and Carbene …
JCK Chu, T Rovis - Angewandte Chemie International Edition, 2018 - Wiley Online Library
The functionalization of C (sp3)− H bonds streamlines chemical synthesis by allowing the
use of simple molecules and providing novel synthetic disconnections. Intensive recent …
use of simple molecules and providing novel synthetic disconnections. Intensive recent …
Synthesis and applications of sodium sulfinates (RSO 2 Na): a powerful building block for the synthesis of organosulfur compounds
RJ Reddy, AH Kumari - RSC advances, 2021 - pubs.rsc.org
This review highlights the preparation of sodium sulfinates (RSO2Na) and their multifaceted
synthetic applications. Substantial progress has been made over the last decade in the …
synthetic applications. Substantial progress has been made over the last decade in the …
Recent advances in the catalytic synthesis of arylsulfonyl compounds
Arylsulfonyl compounds are among the most important compounds in pharmaceutical and
medicinal chemistry. Hence, a wide variety of sulfonylation methods have been reported …
medicinal chemistry. Hence, a wide variety of sulfonylation methods have been reported …
Recent progress and emerging technologies towards a sustainable synthesis of sulfones
S Liang, K Hofman, M Friedrich, J Keller… - …, 2021 - Wiley Online Library
Sulfones play a pivotal role in modern organic chemistry. They are highly versatile building
blocks and find various applications as drugs, agrochemicals, or functional materials …
blocks and find various applications as drugs, agrochemicals, or functional materials …
Visible-light photoredox-catalyzed dual C–C bond cleavage: Synthesis of 2-cyanoalkylsulfonylated 3, 4-dihydronaphthalenes through the insertion of sulfur dioxide
Y Liu, QL Wang, Z Chen, H Li, BQ Xiong… - Chemical …, 2020 - pubs.rsc.org
An efficient novel visible-light photoredox-catalyzed dual carbon–carbon bond cleavage of
methylenecyclopropanes and cycloketone oximes for the synthesis of 2 …
methylenecyclopropanes and cycloketone oximes for the synthesis of 2 …
Copper (i)-catalyzed sulfonylative Suzuki–Miyaura cross-coupling
Using a simple copper (I) catalyst has allowed a high yielding sulfonylative-Suzuki–Miyaura
cross-coupling reaction to be developed. The process provides a single step route to diaryl …
cross-coupling reaction to be developed. The process provides a single step route to diaryl …