Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

N–N linkages are found in many natural compounds and endow fascinating structural and
functional properties. In comparison to the myriad methods for the construction of C–N …

Over the years, alkaloids derived from indole dearomatization, such as indolenine and
indolines have been evolved as promising therapeutic agents due to their important …

Reported herein is a new iron‐catalyzed diastereoselective olefin diazidation reaction which
occurs at room temperature (1–5 mol% of catalysts and dr values of up to> 20: 1). This …

Searching for efficient strategies to access structurally novel aminoindolines is of great
significance for drug discovery. However, catalytic asymmetric de novo construction of …

An iron-catalyzed diastereoselective intermolecular olefin amino-oxygenation reaction is
reported, which proceeds via an iron-nitrenoid generated by the N–O bond cleavage of a …

Alkenes are versatile building blocks in modern organic synthesis. In the difunctionalization
reactions of alkenes, two functional groups can be simultaneously introduced into the π …

Nitrene transfer reactions are powerful tools in synthetic organic chemistry. In recent years,
transition-metal catalyzed nitrene transfer reactions with carbamates as the nitrene …