Hydrogenation is one of the most fundamental transformations in organic synthesis, and its
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …

The aim of this review is to highlight how the diversity generated by N-substitution in the well-
known short-bite ligand bis (diphenylphosphino) amine (DPPA) allows a fine-tuning of the …

The amide is one of the most prevalent functional groups in all of pharmaceuticals, and for
this reason, reactions that introduce the amide moiety are of particular value. Intermolecular …

Diphosphorus ligands connected by a single atom (R2PEPR2; E= CR2, CCR2 and NR) give
chelating ligands with very small bite-angles (natural bite-angle of 72° for dppm) as well as …

Transition‐metal mediated white phosphorus activation is of high interest as an ecological
alternative to P4 chlorination pathway to the practically useful phosphorus products. Herein …

The mechanism of the quinoline transfer hydrogenation (TH) by aqueous HCOOH under the
action of [Cp* Co (quinNH2) I]+(A*; quinNH2= 8-aminoquinoline) has been investigated by a …

Two cis‐1, 2‐diol‐type chiral ligands (T1 and T2) and their tri‐coordinated chiral
dioxaborinane (T (1–2) B (1–2)) and four‐coordinated chiral dioxaborinane adducts with 4 …

A series of new structurally related catechol boronate esters enabled by N→ B dative bond
of general composition (B 1-B 4) and (B 1 NB 4 N) were designed and synthesized for the …

A novel class of tricoordinate dioxaborinane compounds, which have the general formula [B
1 (L 1–5)] and [B 2 (L 1–5)], were designed and synthesized by the corresponding catechol …

This work deals with the synthesis, spectroscopic studies and catalytic evaluation of the
novel chiral salen (L 1 H 2) and (L 2 H 2) ligands and their chiral boronate [L 1 (B 1-4)] and …