Chiral materials: progress, applications, and prospects
Chirality is a universal phenomenon in molecular and biological systems, denoting an
asymmetric configurational property where an object cannot be superimposed onto its mirror …
asymmetric configurational property where an object cannot be superimposed onto its mirror …
Chemical Site-Differentiation of Calix [4] arenes through Enforced Conformations by Confinement in a Cage
K Iizuka, H Takezawa, M Fujita - Journal of the American Chemical …, 2023 - ACS Publications
Desymmetrization of a symmetric skeleton enables late-stage functionalization of molecules.
However, reagent-controlled desymmetrization by site-selective reactions of symmetric …
However, reagent-controlled desymmetrization by site-selective reactions of symmetric …
Synthesis of C60/[10]CPP‐Catenanes by Regioselective, Nanocapsule‐Templated Bingel Bis‐Addition
FM Steudel, E Ubasart, L Leanza… - Angewandte Chemie …, 2023 - Wiley Online Library
The addition of two unsymmetric malonate esters to the Buckminster fullerene C60 can lead
to 22 spectroscopically distinguishable isomeric products and therefore represents a …
to 22 spectroscopically distinguishable isomeric products and therefore represents a …
[HTML][HTML] 1, 3-Diketone calix [4] arene derivatives—A new type of versatile ligands for metal complexes and nanoparticles
SN Podyachev, RR Zairov, AR Mustafina - Molecules, 2021 - mdpi.com
The present review is aimed at highlighting outlooks for cyclophanic 1, 3-diketones as a new
type of versatile ligands and building blocks of the nanomaterial for sensing and bioimaging …
type of versatile ligands and building blocks of the nanomaterial for sensing and bioimaging …
Calix [4] arene–pyrazole conjugates as potential cancer therapeutics
AA Muravev, AD Voloshina, AS Sapunova… - Bioorganic …, 2023 - Elsevier
Tumor selectivity is yet a challenge in chemotherapy-based cancer treatment. A series of
calixarenes derivatized at the lower rim with 3-phenyl-1H-pyrazole units with variable upper …
calixarenes derivatized at the lower rim with 3-phenyl-1H-pyrazole units with variable upper …
Catechol [4] arene: the missing chiral member of the calix [4] arene family
SJ Nemat, H Jedrzejewska, A Prescimone… - Organic …, 2020 - ACS Publications
A missing, inherently chiral member of the calix [4] arene family denoted “catechol [4] arene”
was synthesized. Its properties were studied and compared to the ones of its close relatives …
was synthesized. Its properties were studied and compared to the ones of its close relatives …
[HTML][HTML] Iteroselectivity, the missing sibling of chemo-, regio-, and stereoselectivities
R Lavendomme, I Jabin - Cell Reports Physical Science, 2022 - cell.com
Iteroselectivity is the selectivity that governs the number of repeating chemical
transformations that occur on a substrate bearing multiple identical reactive functions or …
transformations that occur on a substrate bearing multiple identical reactive functions or …
Ready-to-use germanium surfaces for the development of FTIR-based biosensors for proteins
Germanium is particularly suitable for the design of FTIR-based biosensors for proteins. The
grafting of stable and thin organic layers on germanium surfaces remains, however …
grafting of stable and thin organic layers on germanium surfaces remains, however …
Selective Metal‐ion Complexation of a Biomimetic Calix [6] arene Funnel Cavity Functionalized with Phenol or Quinone
P Aoun, N Nyssen, S Richard, F Zhurkin… - … A European Journal, 2023 - Wiley Online Library
In the biomimetic context, many studies have evidenced the importance of the 1st and 2nd
coordination sphere of a metal ion for controlling its properties. Here, we propose to …
coordination sphere of a metal ion for controlling its properties. Here, we propose to …
A rationally designed perfluorinated host for the extraction of PFOA from water utilising non-covalent interactions
H Omorodion, M Palenzuela, M Ruether… - New journal of …, 2018 - pubs.rsc.org
Perfluorooctanoic acid (PFOA) is a persistent organic pollutant and widespread in the
environment. Three hosts have been synthesized based upon the formation of a fluorous …
environment. Three hosts have been synthesized based upon the formation of a fluorous …