Triangulene and its homologues are of considerable interest for molecular spintronics due to
their high-spin ground states as well as the potential for constructing high spin frameworks …

On-surface acetylenic homocoupling has been proposed to construct carbon nanostructures
featuring sp hybridization. However, the efficiency of linear acetylenic coupling is far from …

Metal–alkynyls, an emerging class of functional metal–organic materials, have attracted
widespread attention due to their fascinating properties and multifaceted potential …

Highly unsaturated π-rich carbon skeletons afford versatile tuning of structural and
optoelectronic properties of low-dimensional carbon nanostructures. However, methods …

The combination of alkyne and halogen functional groups in the same molecule allows for
the possibility of many different reactions when utilized in on-surface synthesis. Here, we …

On-surface synthesis provides tools to prepare low-dimensional supramolecular structures.
Traditionally, reactive radicals are a class of single-electron species, serving as exceptional …

Glaser‐like coupling of terminal alkynes by thermal activation is extensively used in on‐
surface chemistry. Here we demonstrate an intramolecular version of this reaction performed …

On‐surface reactions of terminal alkynes in ultrahigh vacuum have attracted widespread
attention due to their high technological promise. However, employing different precursors …

Combining on-surface synthetic methods with the power of scanning tunneling microscopy
to characterize novel materials at the single molecule level, we show how to steer the …

Combining on-surface synthetic methods with the power of scanning tunneling microscopy
to characterize novel materials at the single molecule level, we show how to steer the …