Tuning steric and electronic effects in transition-metal β-diketiminate complexes

C Chen, SM Bellows, PL Holland - Dalton Transactions, 2015 - pubs.rsc.org
β-Diketiminates are widely used supporting ligands for building a range of metal complexes
with different oxidation states, structures, and reactivities. This Perspective summarizes the …

Bulky 2, 6-dibenzhydryl-4-methylphenyl β-diiminato derived complexes of Pd (II) and Cu (II): Efficient catalysts for Suzuki coupling and alcohol oxidation

P Saxena, R Murugavel - Journal of Organometallic Chemistry, 2018 - Elsevier
Reaction of a bulky Schiff base, 2, 6-dibenzhydryl-N-4-((2, 6-dibenzhydryl-4-methylphenyl)
imino) pent-2-en-2-yl)-4-methylaniline (Ar 2 NacNacH (Ar= 2, 6-dibenzhydryl-4 …

Pd and Ni complexes of a novel vinylidene β‐diketimine ligand: Their application as catalysts in Heck coupling and alkyne trimerization

R Beesam, DR Nareddula - Applied Organometallic Chemistry, 2017 - Wiley Online Library
A β‐diketimine ligand with vinylidene substitution at γ‐carbon, CH2C (CH3CNAr) 2 (Ar= 2, 6‐
diisopropylphenyl)(L2), was synthesized by treating β‐diketimine H2C (CH3CNAr) 2 with n …

[PDF][PDF] The balancing act of stabilising high oxidation states of copper and nickel with redox non-innocent ligands containing thiosemicarbazone and dithiocarbazate …

J Bilyj - 2021 - researchgate.net
The use of N, S chelating ligands such as thiosemicarbazides and dithiocarbazates provides
an excellent environment to complex transition metals in a variety of oxidation states …

Synthesis and crystal structure of zinc (II) complexes involving TCNE

M Luo, J Xu, ZJ Zhang, JC Zhang - Координационная химия, 2017 - elibrary.ru
Two novel zinc complexes [Zn (C 10 H 12 N 6 O 8)](I) and [Zn (C 13 H 15 N 5 O 6)](II) were
obtained separately from the direct reaction of tetracyanoethylene (TCNE) with Zn (II) …