The stereoselective photoisomerization of olefins via Energy Transfer (EnT) sensitization
bears significant potential in the context of rational design of catalytic stereodivergent …

Alkenylboronates are versatile building blocks for stereocontrolled synthesis owing to the
traceless nature of the boron group that can be leveraged to achieve highly selective …

A mild, organophotocatalytic N–O bond cleavage of Weinreb amides is disclosed, thereby
expanding the chemistry of this venerable motif beyond acylation. This redox neutral …

Examples of geometric alkene isomerization in nature are often limited to the net exergonic
direction (ΔG°< 0), with the antipodal net endergonic processes (ΔG°> 0) comparatively …

Oximes are valuable synthetic intermediates for the preparation of a variety of functional
groups. To date, the stereoselective synthesis of oximes remains a major challenge, as most …

Configurationally‐defined dienes are pervasive across the bioactive natural product
spectrum, where they typically manifest themselves as sorbic acid‐based fragments. These …

Olefin cross-metathesis is a cornerstone reaction in organic synthesis where
stereoselectivity is typically governed by the structure of the catalyst. In this work, we show …

The visible-light-promoted activation of conjugated C–C double bonds is well developed,
while that of cumulated systems is underexplored. We present the feasibility of this …

Energy transfer plays a special role in photocatalysis by utilizing the potential energy of the
excited state through indirect excitation, in which a photosensitizer determines the …

Acknowledging the crucial role of stereochemistry in fields as diverse as total synthesis,
synthetic methodology, spectroscopy, and the study of the origin of life, the 56 th SCS …