Research progress on polyoxometalate-based transition-metal–rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional …

JW Zhao, YZ Li, LJ Chen, GY Yang - Chemical Communications, 2016 - pubs.rsc.org
With the rapid development of science and technology and the trend of multidisciplinary
pervasion, POM-based TM–RE heterometallic chemistry (POM= polyoxometalate, TM …

[PDF][PDF] Homogeneous-phase electron-transfer reactions of polyoxometalates

IA Weinstock - Chemical reviews, 1998 - fpl.fs.usda.gov
Many isopoly-and heteropolyoxometalate (POM) anions are ideal candidates for the
observation of homogeneous-phase outer-sphere electron-transfer processes and for …

[图书][B] Introduction to green chemistry

J Andraos, AS Matlack - 2022 - taylorfrancis.com
Interest in green chemistry and clean processes has grown so much in recent years that
topics such as fluorous biphasic catalysis, metal organic frameworks, and process …

Mixed-valent Mn supertetrahedra and planar discs as enhanced magnetic coolers

M Manoli, A Collins, S Parsons, A Candini… - Journal of the …, 2008 - ACS Publications
The syntheses and structures of two decametallic mixed-valent Mn supertetrahedra using 2-
amino-2-methyl-1, 3-propanediol (ampH2), two decametallic mixed-valent Mn planar discs …

A family of manganese rods: Syntheses, structures, and magnetic properties

G Rajaraman, M Murugesu, EC Sanudo… - Journal of the …, 2004 - ACS Publications
The reaction of the mixed-valent metal triangles [Mn3O (O2CR) 6 (py) 3](R= CH3, Ph, C
(CH3) 3) with the tripodal ligands H3thme (1, 1, 1-tris (hydroxymethyl) ethane) and H3tmp (1 …

Highly efficient utilization of hydrogen peroxide for selective oxygenation of alkanes catalyzed by diiron-substituted polyoxometalate precursor

N Mizuno, C Nozaki, I Kiyoto… - Journal of the American …, 1998 - ACS Publications
The Keggin-type iron-substituted polyoxometalates have been used as catalysts for the
oxygenation of alkanes in homogeneous reaction media using hydrogen peroxide as an …

Functionalization of polyoxometalates by carboxylato and azido ligands: macromolecular complexes and extended compounds

P Mialane, A Dolbecq, F Sécheresse - Chemical communications, 2006 - pubs.rsc.org
Polyoxometalate compounds continue to be widely studied due to their relevance in various
fields such as catalysis or magnetochemistry. In this article, we will focus on two topics we …

Synthesis, structure, and magnetic properties of a [Mn22] wheel-like single-molecule magnet

M Murugesu, J Raftery, W Wernsdorfer… - Inorganic …, 2004 - ACS Publications
The synthesis and magnetic properties of the compound [Mn22O6 (OMe) 14 (O2CMe) 16
(tmp) 8 (HIm) 2] 1 are reported. Complex 1 was prepared by treatment of [Mn3O (MeCO2) 6 …

A Nonanuclear Copper(II) Polyoxometalate Assembled Around a μ‐1,1,1,3,3,3‐Azido Ligand and Its Parent Tetranuclear Complex

P Mialane, A Dolbecq, J Marrot… - … A European Journal, 2005 - Wiley Online Library
Abstract Reaction of CuII,[γ‐SiW10O36] 8−, and N3− affords three azido polyoxotungstate
complexes. Two of them have been characterized by single‐crystal X‐ray diffraction …

Sandwich-Type Silicotungstates:  Structure and Magnetic Properties of the Dimeric Polyoxoanions [{SiM2W9O34(H2O)}2]12- (M = Mn2+, Cu2+, Zn2+)

U Kortz, S Isber, MH Dickman, D Ravot - Inorganic Chemistry, 2000 - ACS Publications
The novel dimeric silicotungstates [{SiM2W9O34 (H2O)} 2] 12-(M= Mn2+, Cu2+, Zn2+) have
been synthesized and characterized by IR spectroscopy, elemental analysis, and magnetic …