Hydroxymethylfurfural, a versatile platform chemical made from renewable resources

RJ van Putten, JC Van Der Waal, ED De Jong… - Chemical …, 2013 - ACS Publications
Over the last century, the world has become increasingly dependent on oil as its main
source of chemicals and energy. Driven largely by the strong economic growth of India and …

State-of-the-art advances and perspectives in the separation of biomass-derived 5-hydroxymethylfurfural

L Hu, Y Jiang, Z Wu, X Wang, A He, J Xu… - Journal of Cleaner …, 2020 - Elsevier
Effectively converting renewable biomass resources into valuable chemicals is a very
promising and fascinating approach to lower the overreliance on non-renewable fossil …

Insights into the interplay of Lewis and Brønsted acid catalysts in glucose and fructose conversion to 5-(hydroxymethyl) furfural and levulinic acid in aqueous media

V Choudhary, SH Mushrif, C Ho… - Journal of the …, 2013 - ACS Publications
5-(Hydroxymethyl) furfural (HMF) and levulinic acid production from glucose in a cascade of
reactions using a Lewis acid (CrCl3) catalyst together with a Brønsted acid (HCl) catalyst in …

Biomass to furanics: renewable routes to chemicals and fuels

BR Caes, RE Teixeira, KG Knapp… - … Sustainable Chemistry & …, 2015 - ACS Publications
The quest to achieve a sustainable supply of both energy and chemicals is one of the great
challenges of this century. 5-(Hydroxymethyl) furfural (HMF), the long-known dehydration …

Dehydration of glucose to 5-Hydroxymethlyfurfural on bifunctional carbon catalysts

CE Bounoukta, C Megías-Sayago, F Ammari… - Applied Catalysis B …, 2021 - Elsevier
The proposed study tries to reply on one important question concerning glucose
dehydration: What is the role of bare or tandem Lewis/Brønsted acid sites in the reaction and …

Production of levoglucosenone and 5-hydroxymethylfurfural from cellulose in polar aprotic solvent–water mixtures

J He, M Liu, K Huang, TW Walker, CT Maravelias… - Green …, 2017 - pubs.rsc.org
We demonstrate a process to produce levoglucosenone (LGO) and 5-hydroxymethylfurfural
(HMF) from cellulose in up to 65% carbon yield using sulfuric acid as catalyst and a solvent …

Ultrafast flow chemistry for the acid-catalyzed conversion of fructose

P Desir, B Saha, DG Vlachos - Energy & Environmental Science, 2019 - pubs.rsc.org
Biomass conversion to chemicals and fuels has been epitomized by batch processing and
long reaction times that limit the economic viability of future biorefineries and prevent …

Dehydration of fructose and glucose to 5-hydroxymethylfurfural over Al-KCC-1 silica

F Shahangi, AN Chermahini, M Saraji - Journal of energy chemistry, 2018 - Elsevier
In this research, the influence of several factors such as reaction time, catalyst weight,
temperature and different solvents on dehydration reaction of fructose and glucose to 5 …

The Role of Salts and Brønsted Acids in Lewis Acid‐Catalyzed Aqueous‐Phase Glucose Dehydration to 5‐Hydroxymethylfurfural

P Wrigstedt, J Keskiväli, M Leskelä, T Repo - ChemCatChem, 2015 - Wiley Online Library
The effect of salts and Brønsted acids on the Lewis acid (CrCl3⋅ 6 H2O)‐catalyzed glucose
dehydration to 5‐hydroxymethylfurfural (HMF) in aqueous media are described. We show …

On the kinetics of the isomerization of glucose to fructose using Sn-Beta

N Rajabbeigi, AI Torres, CM Lew, B Elyassi… - Chemical Engineering …, 2014 - Elsevier
Process design and techno-economic evaluation of glucose isomerization on Sn-Beta
require reliable catalytic reaction rate expressions and kinetic constants. Here, the …