Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

Conspectus Arynes are highly reactive intermediates having several applications in organic
synthesis for the construction of various ortho-disubstituted arenes. Traditionally, arynes are …

The distortion/interaction model has been used to explain and predict reactivity in a variety
of reactions where more common explanations, such as steric and electronic factors, do not …

Recent developments in aryne chemistry are reviewed with a particular focus on synthetic
methods. This includes an overview of the precursors of arynes and their activators; the …

Sulfonium salts and sulfur ylides are important S (IV) motifs, and have displayed many
unique reactivities to provide simple, effective, and often stereoselective synthesis toward …

抄録< jats: title> Abstract</jats: title>< jats: p> Recent studies of aryne chemistry have left
some unexplained details in their reactivity, reaction mechanisms, and structure‐activity …

The formal C–H bond insertion reaction into aldehydes via 1, 2-hydride shift has been well
established; however, the formal C–C bond insertion is more challenging. In the presence of …

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …

The recent progress made on transformations involving the reactions between aryne
intermediates and organosulfur compounds has been reviewed. A wide variety of aromatic …

We report the first 1, 3-dipolar cycloadditions of 1, 2-cyclohexadiene, a rarely exploited
strained allene. 1, 2-Cyclohexadiene is generated in situ under mild conditions and trapped …