Current advancement in the development of manganese complexes as magnetic resonance imaging probes

S Daksh, A Kaul, S Deep, A Datta - Journal of Inorganic Biochemistry, 2022 - Elsevier
Emerging non-invasive molecular imaging modalities can detect a pathophysiological state
at the molecular level before any anatomic changes are observed. Magnetic resonance …

Sheet-like 2D manganese (IV) complex with high photothermal conversion efficiency

Y Xu, C Li, X Wu, MX Li, Y Ma, H Yang… - Journal of the …, 2022 - ACS Publications
We report a stable, water-soluble, mononuclear manganese (IV) complex [MnIV (H2 L)]·
5H2O (Mn-HDCL) that acts as an efficient photothermal material. This system is based on a …

Complexation of Mn (II) by rigid pyclen diacetates: equilibrium, kinetic, relaxometric, density functional theory, and superoxide dismutase activity studies

Z Garda, E Molnar, N Hamon, JL Barriada… - Inorganic …, 2020 - ACS Publications
We report the Mn (II) complexes with two pyclen-based ligands (pyclen= 3, 6, 9, 15-
tetraazabicyclo [9.3. 1] pentadeca-1 (15), 11, 13-triene) functionalized with acetate pendant …

Thermodynamic stability of Mn (II) complexes with aminocarboxylate ligands analyzed using structural descriptors

R Uzal-Varela, F Pérez-Fernández, L Valencia… - Inorganic …, 2022 - ACS Publications
We present a quantitative analysis of the thermodynamic stabilities of Mn (II) complexes,
defined by the equilibrium constants (log K MnL values) and the values of pMn obtained as …

Coordination-Regulated Terpyridine–Mn (II) Complexes for Photodynamic Therapy Guided by Multiphoton Fluorescence/Magnetic Resonance Imaging

Z Feng, T Zhu, L Wang, T Yuan, Y Jiang… - Inorganic …, 2022 - ACS Publications
The synergy of multiphoton fluorescence imaging (MP-FI) and magnetic resonance imaging
(MRI) provides an imaging platform with high resolution and unlimited penetration depth for …

Synthesis, structure, magnetic properties and thermal behaviour of Ba–M II (M II= Mn, Co, Cu, and Zn) allylmalonates

EN Zorina-Tikhonova, AK Matyukhina… - New Journal of …, 2022 - pubs.rsc.org
A series of Ba–MII complexes with allylmalonic acid anions (Amal)[BaMII (Amal) 2 (H2O) 3] n
(MII= Mn (1), Co (2), Cu (3), and Zn (4)) were synthesized by the reaction of the …

Taking the next step toward inert Mn 2+ complexes of open-chain ligands: the case of the rigid PhDTA ligand

K Pota, Z Garda, FK Kálmán, JL Barriada… - New Journal of …, 2018 - pubs.rsc.org
In line with our research to find inert Mn (II) complexes as contrast agents for magnetic
resonance imaging, we have studied the aromatic-ring rigidified EDTA-analogue o …

Porous Silica Nanospheres with a Confined Mono(aquated) Mn(II)-Complex: A Potential T1T2 Dual Contrast Agent for Magnetic Resonance Imaging

R Mallik, M Saha, C Mukherjee - ACS applied bio materials, 2021 - ACS Publications
Magnetic resonance imaging has emerged as an indispensable imaging modality for the
early-stage diagnosis of many diseases. The imaging in the presence of a contrast agent is …

A new bis (aquated) high relaxivity Mn (II) complex as an alternative to Gd (III)-based MRI contrast agent

B Phukan, C Mukherjee, U Goswami… - Inorganic …, 2018 - ACS Publications
Disclosed here are a piperazine, a pyridine, and two carboxylate groups containing
pentadentate ligand H2pmpa and its corresponding water-soluble Mn (II) complex (1). DFT …

Probing the dynamic behaviour and magnetic identification of seven coordinated Mn (ii) complexes: a combined AIMD and multi-reference approach

N Keot, M Sarma - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
We present an in-depth solution phase dynamics of rare seven coordinated pentagonal
bipyramidal Mn (II) complexes, together with their binding affinity anticipated using ab initio …