Conspectus Interactions between sterically crowded hydrocarbon-substituted ligands are
widely considered to be repulsive because of the intrusion of the electron clouds of the …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Cage-opening reactions of the highly strained tri-tert-butylphosphatetrahedrane (1), shown
here to function as a synthon of (tri-tert-butylcyclopropenyl) phosphinidene, are described …

This exploratory synthesis investigation was undertaken to determine the viability of
replacing a single carbon vertex with another p-block element in a highly strained …

Abstract α‐Diimine ligands have contributed extensively to the coordination chemistry of the
majority of the transition metals; bis (arylimino) acenaphthene ligands (BIANs) have been …

Supramolecular compounds assembled from the heteroleptic tetrahedral complex [{CpMo(CO)
2 } 2 (μ,η 2 -AsSb)] and metal salts - Chemical Communications (RSC Publishing) DOI:10.1039/D4CC01001A …

Compounds containing (pseudo-) tetrahedral main group (semi-) metal units are
fundamentally important in three aspects. First, they provide new strategies for the …

Di-tert-butyldiphosphatetrahedrane (tBuCP) 2 (1) is a mixed carbon-and phosphorus-based
tetrahedral molecule, isolobal to white phosphorus (P4). However, despite the fundamental …

The reactivity of the mixed dipnictogen complexes [{CpMo (CO) 2} 2 (μ, η2: 2‐PE)](E= P, As,
Sb) towards different group 14 electrophiles is reported. The resulting library of cationic …

Phosphatetrahedranes (t BuCP) 2 and (t BuC) 3P were recently reported and represent the
first tetrahedranes containing a mixed carbon/phosphorus core. Herein, we report that …