Catalytic functionalization of alkynes with organoboron reagents provides a straightforward
access to stereochemically defined multisubstituted alkenes, which are structural motifs …

A novel and unusual palladium‐catalyzed [4+ 2] annulation of cyclopropenes with
benzosilacyclobutanes is reported. This reaction occurred through chemoselective Si− C …

Palladium catalysis enables efficient and versatile domino reactions that are initiated by an
intramolecular Mizoroki‐Heck reaction and then terminated by a Suzuki‐Miyaura coupling …

The chemistry of palladium complexes has no limits. Many domino processes (even
multicomponent) are continuously appearing in the literature. Carbocyclic and heterocyclic …

A palladium‐catalyzed strategy is presented to synthesize unsymmetrically linked
heterocycles within stereoselective tetrasubstituted olefins. This reaction is proposed to …

The palladium‐catalyzed silylcyanation of ynamides is described. This reaction is fully
regioselective, delivering tetrasubstituted 2‐aminoacrylonitriles derivatives exclusively …

In comparison with all-carbon parent compounds, the incorporation of Si-element into
carboskeletons generally endows the corresponding sila-analogues with unique biological …

The intra-and intermolecular synthesis of selenium-substituted acyclic and heterocyclic
acrylonitrile derivatives is presented. The 1, 2-difunctionalization of several internal alkynes …

A palladium-catalyzed intramolecular formal anti-carboamination of internal alkynes for the
synthesis of tetrasubstituted enamines and pyrroles is reported. A broad range of different …

Enantioselective synthesis of all‐carbon quaternary centers remains a considerable
challenge for synthetic organic chemists. Here, we report a two‐step protocol to synthesize …