Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways
WI Dzik, PP Lange, LJ Goossen - Chemical Science, 2012 - pubs.rsc.org
This tutorial review provides a comparison between the concepts of catalytic decarboxylative
and decarbonylative couplings for the ipso-substitution of carboxylate groups, and illustrates …
and decarbonylative couplings for the ipso-substitution of carboxylate groups, and illustrates …
Partial reductions of carboxylic acids and their derivatives to aldehydes
Z Yang - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
The one-pot reductive synthesis of aldehydes from carboxylic acids and their derivatives
without the formation of alkanol intermediates, in a redox-economical fashion, is …
without the formation of alkanol intermediates, in a redox-economical fashion, is …
Transition metal catalyzed carbonylation reactions
M Beller, XF Wu - Chemical Science Edge Article Springer, 2013 - Springer
Homogenous catalyst plays an important role in modern organic synthesis, especially now
that more focus is being placed the development of sustainable chemistry. With the …
that more focus is being placed the development of sustainable chemistry. With the …
Selective Reduction of Carboxylic Acids to Aldehydes Catalyzed by B(C6F5)3
D Bézier, S Park, M Brookhart - Organic letters, 2013 - ACS Publications
B (C6F5) 3 efficiently catalyzes hydrosilylation of aliphatic and aromatic carboxylic acids to
produce disilyl acetals under mild conditions. Catalyst loadings can be as low as 0.05 mol …
produce disilyl acetals under mild conditions. Catalyst loadings can be as low as 0.05 mol …
Facile, green, and functional group-tolerant reductions of carboxylic acids… in, or with, water
KS Iyer, C Nelson, BH Lipshutz - Green Chemistry, 2023 - pubs.rsc.org
Facile reductions of carboxylic acids to aldehydes or alcohols can be effected under mild
conditions upon initial conversion to their corresponding S-2-pyridyl thioesters. Upon …
conditions upon initial conversion to their corresponding S-2-pyridyl thioesters. Upon …
Competent production of hydrogen and hydrogenation of carboxylic acids using urea-rich waste water over visible-light-responsive rare earth doped photocatalyst
Background A strategy employing water as a hydrogen source is promising but challenging.
Conversely, urea is the major pollutants causing substantial water pollution. Moreover, direct …
Conversely, urea is the major pollutants causing substantial water pollution. Moreover, direct …
Environmentally‐friendly lithium recycling from a spent organic li‐ion battery
A simple and straightforward method using non‐polluting solvents and a single thermal
treatment step at moderate temperature was investigated as an environmentally‐friendly …
treatment step at moderate temperature was investigated as an environmentally‐friendly …
Nickel-Catalyzed Selective Reduction of Carboxylic Acids to Aldehydes
AV Iosub, S Moravčík, CJ Wallentin, J Bergman - Organic letters, 2019 - ACS Publications
The direct reduction of carboxylic acids to aldehydes is a fundamental transformation in
organic synthesis. The combination of an air-stable Ni precatalyst, dimethyl dicarbonate as …
organic synthesis. The combination of an air-stable Ni precatalyst, dimethyl dicarbonate as …
Achievement of regioselectivity in transition metal-catalyzed direct C–H (hetero) arylation reactions of heteroarenes with one heteroatom through the use of removable …
The transition metal-catalyzed direct C–H (hetero) arylation reactions of heteroarenes are
currently one of the hottest topics of synthetic organic chemistry. In fact, these reactions …
currently one of the hottest topics of synthetic organic chemistry. In fact, these reactions …
Rhodium‐Catalyzed Decarbonylative Direct C2‐Arylation of Indoles with Aryl Carboxylic Acids
L Zhang, X Xue, C Xu, Y Pan, G Zhang, L Xu… - …, 2014 - Wiley Online Library
A RhI‐catalyzed direct C2‐arylation of indoles with diversely substituted aryl carboxylic
acids has been developed using 2‐pyrimidyl group as an easily installable and readily …
acids has been developed using 2‐pyrimidyl group as an easily installable and readily …