Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities

C Wu, N Corrigan, CH Lim, W Liu, G Miyake… - Chemical …, 2022 - ACS Publications
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …

PET-RAFT polymerization: Mechanistic perspectives for future materials

ML Allegrezza, D Konkolewicz - ACS Macro Letters, 2021 - ACS Publications
In the past decade, photochemistry has emerged as a growing area in organic and polymer
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …

A Photoinduced Dual‐Wavelength Approach for 3D Printing and Self‐Healing of Thermosetting Materials

Z Zhang, N Corrigan, C Boyer - Angewandte Chemie, 2022 - Wiley Online Library
Vat photopolymerization‐based 3D printing techniques have been widely used to produce
high‐resolution 3D thermosetting materials. However, the lack of repairability of these …

The emergence of reversible–deactivation radical polymerization in 3D printing

VA Bobrin, J Zhang, N Corrigan… - Advanced Materials …, 2023 - Wiley Online Library
The majority of materials 3D printed using vat photopolymerization techniques are prepared
by uncontrolled polymerization methods and cannot be easily modified to introduce …

Application of RAFT in 3D printing: where are the future opportunities?

A Bagheri - Macromolecules, 2023 - ACS Publications
Research into 3D printing using reversible addition–fragmentation chain transfer (RAFT)
polymerization has garnered interest since it was first reported in 2019. This technique was …

Xanthate-based photoiniferter RAFT polymerization toward oxygen-tolerant and rapid living 3D printing

B Zhao, J Li, Y Xiu, X Pan, Z Zhang, J Zhu - Macromolecules, 2022 - ACS Publications
Three-dimensional (3D) printing based on photoinduced reversible addition–fragmentation
chain transfer (RAFT) polymerization is emerging as a versatile and powerful method to …

Exploiting the Monomer-Feeding Mechanism of RAFT Emulsion Polymerization for Polymerization-Induced Self-Assembly of Asymmetric Divinyl Monomers

J Zhou, Q Huang, L Zhang, J Tan - ACS Macro Letters, 2023 - ACS Publications
We exploited the monomer-feeding mechanism of reversible addition–fragmentation chain
transfer (RAFT) emulsion polymerization to achieve the successful polymerization-induced …

Visible light induced high resolution and swift 3D printing system by halogen atom transfer

W Tomal, HC Kiliclar, P Fiedor, J Ortyl… - Macromolecular rapid …, 2023 - Wiley Online Library
Abstract 3D printing technology offers solutions for numerous needs in industry and the daily
life of individuals. In recent years, most research efforts have focused on this technology as …

Self-healing hydrogel scaffolds through PET-RAFT polymerization in cellular environment

ADM Rigby, AR Alipio, V Chiaradia… - Biomacromolecules, 2023 - ACS Publications
Photo electron/energy transfer-reversible addition–fragmentation chain transfer (PET-RAFT)
has emerged as a powerful reversible-deactivation radical polymerization technique …