Confining enzymes in porous organic frameworks: from synthetic strategy and characterization to healthcare applications

S Huang, G Chen, G Ouyang - Chemical Society Reviews, 2022 - pubs.rsc.org
Enzymes are a class of natural catalysts with high efficiency, specificity, and selectivity
unmatched by their synthetic counterparts and dictate a myriad of reactions that constitute …

Tribochemistry, mechanical alloying, mechanochemistry: what is in a name?

AAL Michalchuk, EV Boldyreva, AM Belenguer… - Frontiers in …, 2021 - frontiersin.org
Over the decades, the application of mechanical force to influence chemical reactions has
been called by various names: mechanochemistry, tribochemistry, mechanical alloying, to …

Time‐resolved in situ monitoring of mechanochemical reactions

AAL Michalchuk, F Emmerling - … Chemie International Edition, 2022 - Wiley Online Library
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …

Theoretical and experimental advances in high-pressure behaviors of nanoparticles

L Meng, TV Vu, LJ Criscenti, TA Ho, Y Qin… - Chemical …, 2023 - ACS Publications
Using compressive mechanical forces, such as pressure, to induce crystallographic phase
transitions and mesostructural changes while modulating material properties in …

[HTML][HTML] High throughput tabletop shock techniques and measurements

F Li, DD Dlott - Journal of Applied Physics, 2022 - pubs.aip.org
Although shock experiments are traditionally performed in large facilities, tabletop
experiments that provide convenient high-throughput shock testing have been growing in …

Intergranular hotspots: A molecular dynamics study on the influence of compressive and shear work

BW Hamilton, MP Kroonblawd… - The Journal of …, 2023 - ACS Publications
Numerous crystal-and microstructural-level mechanisms are at play in the formation of
hotspots, which are known to govern high explosives initiation behavior. Most of these …

Enhanced Mechanical Stability and Proton Conductivity Performance from the Dense Mn (II)-Metal–Organic Framework to Porous Mn (II)–Fe (III)-Metal–Organic …

ZY Zhang, GX Qin, XM Li, HL Dong, S Wan… - Inorganic …, 2022 - ACS Publications
Postsynthetic modification (PSM) of the metal–organic framework (MOF) has been
demonstrated to be an effective strategy to enhance performance. In this particular work, the …

ZIF-75 under pressure: Negative linear compressibility and pressure-induced instability

F Colmenero, V Timón - Applied Sciences, 2022 - mdpi.com
Featured Application The zeolitic imidazolate framework ZIF-75 exhibits the negative linear
compressibility effect under small applied pressures with multiple potential applications …

From Ductile to Brittle: Defect-Engineered Mechanical Properties of Metal–Organic Frameworks

B Wang, J Ke, H Huang, P Ren… - ACS Applied Materials & …, 2024 - ACS Publications
The introduction of defects in metal–organic frameworks (MOFs) is an effective method to
improve the performance of MOFs in many applications, but it also compromises the …

Anomalous Loading Rate Dependence of the Mechanical Properties of Metal–Organic Framework Crystals: Latent Heat Effects of the Pressure-Induced Local Phase …

B Wang, J Ke, X Chen, Y Sun, P Ren… - The Journal of Physical …, 2023 - ACS Publications
The loading rate dependence of the mechanical properties of metal–organic framework
(MOF) crystals is key in determining their performance in many engineering applications …