Metal-Free H2 Activation for Highly Selective Hydrogenation of Nitroaromatics Using Phosphorus-Doped Carbon Nanotubes

X Chen, Q Shen, Z Li, W Wan, J Chen… - ACS applied materials …, 2019 - ACS Publications
We reported that phosphorus-doped carbon nanotubes (P-CNTs), showing metal-like
properties, can efficiently promote metal-free hydrogenation of nitrobenzene (1a) to aniline …

C2H2 hydrochlorination over the diatomic RuM catalysts anchored over the N-doped graphene: Influences of metal M type and coordination environment

Y Zhou, Y Wang, L Ling, B Wang, R Zhang - Applied Surface Science, 2022 - Elsevier
Catalytic performance of N-doped graphene supported diatomic catalysts is closely related
to the coordination environment and the metal types of active center. In this work, the …

Theoretical design of ruthenium single-atom catalysts with different substrates for acetylene hydrochlorination

Y Jia, Y Nian, J Zhang, Y Han - Molecular Catalysis, 2021 - Elsevier
Ruthenium-based catalysts exhibit excellent catalyst activity in the acetylene
hydrochlorination reaction and tend to be a good substitute for mercury-based catalysts due …

Nitrogen-doped porous carbon from biomass with superior catalytic performance for acetylene hydrochlorination

Z Shen, Y Liu, Y Han, Y Qin, J Li, P Xing, B Jiang - RSC advances, 2020 - pubs.rsc.org
Acetylene hydrochlorination is an important aspect of the industrial synthesis of polyvinyl
chloride, but it requires a toxic mercury chloride catalyst. Here we report a green, highly …

The Catalytic Mechanism of [Bmim] Cl-Transition Metal Catalysts for Hydrochlorination of Acetylene

H Shao, Y Lu, X Liang, C Li - Catalysts, 2024 - mdpi.com
Ionic liquids (ILs) are green solvents involved in chemical reaction and separation
processes. In this paper, four ILs-based metal catalysts were prepared by dissolving four …

Ionic liquid–solvent systems in the gas–liquid phase for acetylene hydrochlorination

X Wang, Y Li, Z Zhang, Z Wang, Z Zhang… - New Journal of …, 2024 - pubs.rsc.org
Homogeneous mercury-free catalysts synthesized using ionic liquids (ILs) have become
increasingly popular due to their high activity and excellent stability for acetylene …

[HTML][HTML] Mechanism exploring of acetylene hydrochlorination using hexamethylenetetramine as a single active site metal-free catalyst

X Liu, X Qiao, Z Zhou, C Zhao, Q Guan, W Li - Catalysis Communications, 2020 - Elsevier
An activated carbon (AC) supported hexamethylenetetramine (HMT), with a single tertiary
amine N active site, was proposed to be used as a novel metal-free catalyst for acetylene …

Constructing the single‐site of pyridine‐based organic compounds for acetylene hydrochlorination: From theory to experiment

C Zhao, Z Yi, Y Xue, Q Guan… - Applied Organometallic …, 2021 - Wiley Online Library
Acetylene hydrochlorination reaction requires toxic mercuric chloride catalyst, which caused
serious environmental pollution by mercury in recent years. Though Au‐based catalysts …