Ab initio simulations of water/metal interfaces

A Groß, S Sakong - Chemical reviews, 2022 - ACS Publications
Structures and processes at water/metal interfaces play an important technological role in
electrochemical energy conversion and storage, photoconversion, sensors, and corrosion …

Dynamic relaxations and relaxation-property relationships in metallic glasses

WH Wang - Progress in Materials Science, 2019 - Elsevier
Dynamic relaxation is an intrinsic and universal feature of glasses and enables fluctuation
and dissipation to occur, which induces plentiful behaviour, maintains equilibrium, and …

Nuclear quantum effects enter the mainstream

TE Markland, M Ceriotti - Nature Reviews Chemistry, 2018 - nature.com
Atomistic simulations of chemical, biological and materials systems have become
increasingly precise and predictive owing to the development of accurate and efficient …

[HTML][HTML] Perspective: How good is DFT for water?

MJ Gillan, D Alfe, A Michaelides - The Journal of chemical physics, 2016 - pubs.aip.org
Kohn-Sham density functional theory (DFT) has become established as an indispensable
tool for investigating aqueous systems of all kinds, including those important in chemistry …

Nuclear quantum effects in water and aqueous systems: Experiment, theory, and current challenges

M Ceriotti, W Fang, PG Kusalik, RH McKenzie… - Chemical …, 2016 - ACS Publications
Nuclear quantum effects influence the structure and dynamics of hydrogen-bonded systems,
such as water, which impacts their observed properties with widely varying magnitudes. This …

Ab initio theory and modeling of water

M Chen, HY Ko, RC Remsing… - Proceedings of the …, 2017 - National Acad Sciences
Water is of the utmost importance for life and technology. However, a genuinely predictive
ab initio model of water has eluded scientists. We demonstrate that a fully ab initio approach …

Ab initio thermodynamics of liquid and solid water

B Cheng, EA Engel, J Behler… - Proceedings of the …, 2019 - National Acad Sciences
Thermodynamic properties of liquid water as well as hexagonal (Ih) and cubic (Ic) ice are
predicted based on density functional theory at the hybrid-functional level, rigorously taking …

Protons and hydroxide ions in aqueous systems

N Agmon, HJ Bakker, RK Campen… - Chemical …, 2016 - ACS Publications
Understanding the structure and dynamics of water's constituent ions, proton and hydroxide,
has been a subject of numerous experimental and theoretical studies over the last century …

How van der Waals interactions determine the unique properties of water

T Morawietz, A Singraber… - Proceedings of the …, 2016 - National Acad Sciences
Whereas the interactions between water molecules are dominated by strongly directional
hydrogen bonds (HBs), it was recently proposed that relatively weak, isotropic van der …

Free energy of proton transfer at the water–TiO 2 interface from ab initio deep potential molecular dynamics

MFC Andrade, HY Ko, L Zhang, R Car, A Selloni - Chemical Science, 2020 - pubs.rsc.org
TiO2 is a widely used photocatalyst in science and technology and its interface with water is
important in fields ranging from geochemistry to biomedicine. Yet, it is still unclear whether …