Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

[HTML][HTML] Macroheterocyclic compounds a key building block in new functional materials and molecular devices

OI Koifman, TA Ageeva, IP Beletskaya… - …, 2020 - cyberleninka.ru
The review discusses the latest advances in the directed synthesis and application of
macroheterocyclic compounds in science, engineering and technology, viz. as catalysts for …

NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions

YG Gorbunova, AG Martynov, KP Birin… - Russian Journal of …, 2021 - Springer
Coordination compounds of lanthanides attract increasing attention of researchers due to
their unique physical and chemical properties, including interesting optical and magnetic …

Comparison of the magnetic anisotropy and spin relaxation phenomenon of dinuclear terbium (III) phthalocyaninato single-molecule magnets using the geometric spin …

T Morita, M Damjanović, K Katoh… - Journal of the …, 2018 - ACS Publications
Herein we report the synthesis and characterization of a dinuclear TbIII single-molecule
magnet (SMM) with two [TbPc2] 0 units connected via a fused-phthalocyaninato ligand. The …

NMR thermosensing properties on binuclear triple-decker complexes of terbium (III) and dysprosium (III) with 15-crown-5-phthalocyanine

SP Babailov, MA Polovkova, GA Kirakosyan… - Sensors and Actuators A …, 2021 - Elsevier
In this paper, we have firstly demonstrated the thermosensing properties of binuclear triple-
decker terbium (III) and dysprosium (III) complexes with 15-crown-5-phthalocyanine Tb 2 …

Cation-induced dimerization of heteroleptic crown-substituted trisphthalocyaninates as revealed by X-ray diffraction and NMR spectroscopy

AG Martynov, MA Polovkova, GS Berezhnoy… - Inorganic …, 2020 - ACS Publications
We report comprehensive X-ray diffraction and NMR studies of potassium-induced
dimerization of heteroleptic triple-decker crown-phthalocyaninates [(15C5) 4Pc] M (Pc) M …

Solvation-Induced Conformational Switching of Trisphthalocyanates for Control of Their Magnetic Properties

AG Martynov, AA Sinelshchikova… - Inorganic …, 2023 - ACS Publications
Stabilization of different conformers of sandwich phthalocyaninates by changing the
solvation environment has been demonstrated with the examples of new heteroleptic yttrium …

Redox-Triggered Switching of Conformational State in Triple-Decker Lanthanide Phthalocyaninates

AG Martynov, MA Polovkova, YG Gorbunova… - Molecules, 2022 - mdpi.com
Double-and triple-decker lanthanide phthalocyaninates exhibit unique physical-chemical
properties, particularly single-molecule magnetism. Among other factors, the magnetic …

Sorting phenomena and chirality transfer in fluoride-bridged macrocyclic rare earth complexes

K Ślepokura, TA Cabreros, G Muller… - Inorganic …, 2021 - ACS Publications
The reaction of fluoride anions with mononuclear lanthanide (III) and yttrium (III) hexaaza-
macrocyclic complexes results in the formation of dinuclear fluoride-bridged complexes. As …

Paramagnetic encoding of molecules

J Kretschmer, T David, M Dračínský, O Socha… - Nature …, 2022 - nature.com
Contactless digital tags are increasingly penetrating into many areas of human activities.
Digitalization of our environment requires an ever growing number of objects to be identified …