Reactions between ruthenium cluster carbonyls and 1, 4-diphenylbuta-1, 3-diyne

MI Bruce, NN Zaitseva, BW Skelton, AH White - Inorganica chimica acta, 1996 - Elsevier
The complexes RuC (C CPh) CPhC (C CPh) CPh (CO) 3 (NMe3)(3), Ru2μ-C (C
CPh) CPhC (C CPh) CPh (CO) 6 (1), Ru2μ-[C (C CPh) CPh] 2CO (CO) 6 (2), Ru3 …

Self-Activation of a Cluster-Bound Alkyne toward Carbon− Carbon Bond Forming Reactions

S Rivomanana, C Mongin, G Lavigne - Organometallics, 1996 - ACS Publications
The methanol-catalyzed elimination of Cl-from the “activated” anionic species [PPN][Ru3 (μ-
Cl)(μ-PhCCPh)(CO) 9](1) in the presence of bis (diphenylphosphino) methane (dppm) …

Enyne and Butatriene Ligands from the Reaction of Diynes on the Square Face of the Hydrido Phosphinidene Cluster (. mu.-H) 2Ru4 (CO) 12 (. mu. 3-PPh)

JF Corrigan, NJ Taylor, AJ Carty - Organometallics, 1994 - ACS Publications
Diphenylbutadiyne reacts with the 62-electron cluster nido-(fi-H) 2Ru4 (CO) i2 (fi3-PPh)(1) to
afford Ru4 (CO) 1iti4-r] 1: r] 1: r} 1: rf-P (Ph) C {C (H) Ph) CC (H) Ph](2), Ru4 (CO) 1d (g …

Heteronuclear Triangular Clusters of the Type [Pt2M(μ3112-PhC⋮CC⋮CPh)(CO)5(PPh3)2] (M = Fe or Ru)

S Yamazaki, AJ Deeming, DM Speel - Organometallics, 1998 - ACS Publications
The 46-electron heteronuclear clusters [Pt2M (μ3-η1: η1: η2-PhC⋮ CC⋮ CPh)(CO) 5 (PPh3)
2](M= Fe or Ru) are formed in moderate yield by treating [Pt (η2-PhC⋮ CC⋮ CPh)(PPh3) 2] …

Activation of Tri(2-furyl)phosphine by [Ru4(μ-H)4(CO)12]:  The First Example of Coordinated Furyl and Furyne Ligands at Tetraruthenium Phosphide and …

WY Wong, FL Ting, Z Lin - Organometallics, 2003 - ACS Publications
Tri (2-furyl) phosphine (PFu3) reacts with [Ru4 (μ-H) 4 (CO) 12](1) in refluxing THF to give,
apart from an isomeric pair of the substituton products [Ru4 (μ-H) 4 (CO) 10 (PFu3) 2](2a …

Reactions of [Os3 (CO) 10 (NCMe) 2] with symmetric diynes and their reactivity towards [Co2 (CO) 8]

AJ Amoroso, LP Clarke, JE Davies, J Lewis… - Journal of …, 2001 - Elsevier
The reaction between [Os3 (CO) 10 (NCMe) 2] and MeC2C2Me yields the known cluster
[Os3 (CO) 9 (μ-CO)(μ3-η2-MeC2C2Me)](1) and three previously uncharacterised products …

Rearrangements of alkyne and 1, 3-diyne in transition metal center forming small ring complexes

S Yamazaki - Inorganica Chimica Acta, 2011 - Elsevier
CC bond coupling of alkynes (s) and alkynyl (s) mediated by transition metal complexes
have recently lead to isolations of the small organometallic ring constituted of unsaturated …

Early High Oxidation State− Late Low Oxidation State Mixed-Metal Organometallics: Examples of Oxo-Bridged Tungsten− Ruthenium Acetylide Clusters

P Blenkiron, AJ Carty, SM Peng, GH Lee, CJ Su… - …, 1997 - ACS Publications
The heterometallic complexes (C5Me5) W (O) 2Ru4 (CO) 10 (μ4-PPh)(CCPh)(1),(C5Me5) W
(O) 2Ru4 (CO) 7 (C7H8)(μ4-PPh)(CCPh)(2), and (C5Me5) W (O) 2Ru5 (CO) 12 (μ4 …

Reactions of Diacetylene Ligands with Trinuclear Clusters. 3. Cyclization of Diynes with β-Amino Moieties on the Metal Core of [H2Os3(CO)10]

SP Tunik, VD Khripun, IA Balova, E Nordlander… - …, 2001 - ACS Publications
Reactions of [H2Os3 (CO) 10] with the substituted diynes R− C2− C2− R '(1, R= Ph, R '=
CH2NHPh; 2, R= Ph, R '= CH2NHCH2Ph; 3, R= R '= CH2NHPh) afford the clusters [HOs3 …

Reactions of [H2Os3 (CO) 10] with Conjugated Diynes (RC2C2R ') Containing Nucleophilic Oxygen in β Position of a Substituent (R= Ph, R '= CH2OH, C (O) Ph; R= R …

SP Tunik, VD Khripoun, IA Balova, ME Borovitov… - …, 2003 - ACS Publications
Reactions of [H2Os3 (CO) 10] with a series of diynes, RC2C2R '(1: R= Ph, R '= CH2OH; 2:
R= Ph, R '= C (O) Ph; 3: R= R '= C (OH) Me2), have been studied. It was found that upon …