Covalent organic frameworks for photocatalysis: Synthesis, structural features, fundamentals and performance
YN Gong, X Guan, HL Jiang - Coordination Chemistry Reviews, 2023 - Elsevier
Covalent organic frameworks (COFs) are a new class of crystalline porous materials
obtained from covalently attached organic building units. By virtue of the unique …
obtained from covalently attached organic building units. By virtue of the unique …
Emerging low-nuclearity supported metal catalysts with atomic level precision for efficient heterogeneous catalysis
X Zheng, B Li, Q Wang, D Wang, Y Li - Nano research, 2022 - Springer
Supported atomically dispersed metal catalysts (ADMCs) have received enormous attention
due to their high atom utilization efficiency, mass activity and excellent selectivity. Single …
due to their high atom utilization efficiency, mass activity and excellent selectivity. Single …
Active hydrogen boosts electrochemical nitrate reduction to ammonia
Electrochemical nitrate reduction to ammonia is a promising alternative strategy to the
traditional Haber-Bosch process but suffers from a low Faradaic efficiency and limited …
traditional Haber-Bosch process but suffers from a low Faradaic efficiency and limited …
Recent progress in electrocatalytic nitrogen reduction to ammonia (NRR)
Ammonia is an essential raw ingredient for fertilizers, a carbon-free hydrogen carrier, and an
alternative fuel. The natural process of producing ammonia cannot meet the rapidly growing …
alternative fuel. The natural process of producing ammonia cannot meet the rapidly growing …
Construction of C–N bonds from small-molecule precursors through heterogeneous electrocatalysis
J Li, Y Zhang, K Kuruvinashetti… - Nature Reviews Chemistry, 2022 - nature.com
Energy-intensive thermochemical processes within chemical manufacturing are a major
contributor to global CO2 emissions. With the increasing push for sustainability, the scientific …
contributor to global CO2 emissions. With the increasing push for sustainability, the scientific …
Electronic state and microenvironment modulation of metal nanoparticles stabilized by MOFs for boosting electrocatalytic nitrogen reduction
Modulation of the local electronic structure and microenvironment of catalytic metal sites
plays a critical role in electrocatalysis, yet remains a grand challenge. Herein, PdCu …
plays a critical role in electrocatalysis, yet remains a grand challenge. Herein, PdCu …
Covalent organic frameworks towards photocatalytic applications: Design principles, achievements, and opportunities
As a subclass of porous framework materials, covalent organic frameworks (COFs) feature
permanent porosity, long-range order, and rigid backbones, and offer an important material …
permanent porosity, long-range order, and rigid backbones, and offer an important material …
Efficient C–N coupling in the direct synthesis of urea from CO2 and N2 by amorphous SbxBi1-xOy clusters
Although direct generation of high-value complex molecules and feedstock by coupling of
ubiquitous small molecules such as CO2 and N2 holds great appeal as a potential …
ubiquitous small molecules such as CO2 and N2 holds great appeal as a potential …
Optimizing intermediate adsorption via heteroatom ensemble effect over RuFe bimetallic alloy for enhanced nitrate electroreduction to ammonia
The electrochemical nitrate reduction reaction (NO3RR) is a promising approach for nitrate
removal and NH3 synthesis at ambient conditions. As a complex eight‐electron/nine‐proton …
removal and NH3 synthesis at ambient conditions. As a complex eight‐electron/nine‐proton …
In situ construction of metal–organic frameworks as smart channels for the effective electrocatalytic reduction of nitrate at ultralow concentrations to ammonia
Electrochemical conversion of nitrate, a widespread water pollutant, into high-value-added
ammonia is a renewable and delocalized route to restore the globally perturbed nitrogen …
ammonia is a renewable and delocalized route to restore the globally perturbed nitrogen …