Multidentate unsymmetrically-substituted Schiff bases and their metal complexes: Synthesis, functional materials properties, and applications to catalysis

X Liu, C Manzur, N Novoa, S Celedón, D Carrillo… - Coordination Chemistry …, 2018 - Elsevier
This review focuses on the recent developments of unsymmetrically-substituted multidentate
Schiff bases whose steric and electronic characteristics are easily manipulated by selecting …

Rational approach to polymer-supported catalysts: synergy between catalytic reaction mechanism and polymer design

N Madhavan, CW Jones, M Weck - Accounts of chemical research, 2008 - ACS Publications
Supported catalysis is emerging as a cornerstone of transition metal catalysis, as
environmental awareness necessitates “green” methodologies and transition metal …

Aluminum and yttrium complexes of an unsymmetrical mixed fluorous alkoxy/phenoxy-diimino ligand: synthesis, structure, and ring-opening polymerization catalysis

A Alaaeddine, CM Thomas, T Roisnel… - …, 2009 - ACS Publications
The coordination chemistry of the new unsymmetrical Schiff base ligand {(3, 5-t Bu2-1-
OC6H4) CH N (trans-1, 2-cyclo-C6H10) N C (Me) CH2C (CF3) 2O} 2−({ArONCyNOCF3} …

Ring-expanding olefin metathesis: A route to highly active unsymmetrical macrocyclic oligomeric co-salen catalysts for the hydrolytic kinetic resolution of epoxides

X Zheng, CW Jones, M Weck - Journal of the American Chemical …, 2007 - ACS Publications
In the presence of the third generation Grubbs catalyst, the ring-expanding olefin metathesis
of a monocyclooct-4-en-1-yl functionalized salen ligand and the corresponding Co (II)(salen) …

Nonsymmetrical salen ligands and their complexes: synthesis and applications

AW Kleij - European Journal of Inorganic Chemistry, 2009 - Wiley Online Library
The importance of salen ligands in homogeneous catalysis and material chemistry has
unambiguously been demonstrated over the last two decades. In the majority of the existing …

When the metal makes the difference: Template syntheses of tridentate and tetradentate salen-type schiff base ligands and related complexes

R Mazzoni, F Roncaglia, L Rigamonti - Crystals, 2021 - mdpi.com
The reaction of organic molecules mediated by a metal center (template synthesis) can
result in a final connectivity that may differ from the one obtained in the absence of the metal …

Poly (styrene)‐Supported Co–Salen Complexes as Efficient Recyclable Catalysts for the Hydrolytic Kinetic Resolution of Epichlorohydrin

X Zheng, CW Jones, M Weck - Chemistry–A European Journal, 2006 - Wiley Online Library
Here we describe an unprecedented synthetic approach to poly (styrene)‐supported chiral
salen ligands by the free radical polymerization of an unsymmetrical styryl‐substituted salen …

A practical one-pot synthesis of enantiopure unsymmetrical salen ligands

M Holbach, X Zheng, C Burd, CW Jones… - The Journal of Organic …, 2006 - ACS Publications
A practical, one-pot synthesis of enantiopure unsymmetrical salen ligands is described,
using a 1: 1: 1 molar ratio of a chiral diamine and two different salicylaldehydes. The new …

Recent advances and perspectives in the manganese-catalysed epoxidation reactions

KK Krishnan, AM Thomas, KS Sindhu, G Anilkumar - Tetrahedron, 2016 - Elsevier
Metal-catalysed oxidation is one of the most important reactions in chemistry and biology. 1
In particular, transition metal complex-catalysed epoxidation of olefins is of increasing …

Design and synthesis of Schiff base homobimetallic-complexes as promising antimicrobial agents

M Pervaiz, A Sadiq, S Sadiq, Z Saeed, M Imran… - Inorganic Chemistry …, 2022 - Elsevier
Multidrug-resistant pathogens such as MRSA (Methicillin-resistant Staphylococcus aureus)
have challenged the potency of current antimicrobial drugs. The Schiff bases are weighed …